Not if Congress approves. Remember West Virginia was built from an existing state.
Wrong.
the
western part of the state of
Virginia (1776–1863), whose population became sharply divided over the issue of secession from the Union and in the separation from
Virginia, formalized by admittance to the Union as a new state in 1863.
- West Virginia formed after breaking away from Virginia during the Civil War. ...
Virginia succeeded from the united states. Thus was no longer a state. Congress didn't divide it, the people broke away from the rebels, and congress admitted those still loyal to the USA.