in light of the fact that if we were to burn every rock on this planet we could only lower the pH from 8.1 to 8.0 I too am wondering!
Do you have a reference for that "fact"?
As it does not jibe well with points like:
Evidence for carbon addition
Clear evidence for massive addition of 13C-depleted carbon at the onset of the PETM comes from two observations. First, a prominent negative excursion in the carbon isotope composition (δ13C) of carbon-bearing phases characterizes the PETM in numerous (>130) widespread locations from a range of environments.[5] Second, carbonate dissolution marks the PETM in sections from the deep-sea.
The total mass of carbon injected to the ocean and atmosphere during the PETM remains the source of debate. In theory, it can be estimated from the magnitude of the negative CIE, the amount of carbonate dissolution on the seafloor, or ideally both.[4][16] However, the shift in the δ13C across the PETM depends on the location and the carbon-bearing phase analyzed. In some records of bulk carbonate, it is about 2‰; in some records of terrestrial carbonate or organic matter it exceeds 6‰.[5][17] Carbonate dissolution also varies throughout different ocean basins. It was extreme in parts of the north and central Atlantic Ocean but far less pronounced in the Pacific Ocean[16][18] .[19] With available information, estimates of the carbon addition range from about 2000 to 7000 gigatons.[16][18][19]
from https://en.wikipedia.org/wiki/Paleocene-Eocene_Thermal_Maximum
Do you think lowering the ocean's pH from 8.1 to 8.0 would dissolve the world's carbonate sediments? I don't. Yet that's precisely what happened during the PETM.
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