I am not trying to convert you, but I am trying to make sure that no unwary reader thinks your bizarre theory of prohibited emission is correct.
You are doing even worse. You are attempting to mislead people who are not even in the conversation.
I have no bizarre theory. It is you who is operating on unproven theory and hypothesis. My argument is that Second Law of Thermodynamics says:
It is not possible for heat to flow from a colder body to a warmer body without any work having been done to accomplish this flow. Energy will not flow spontaneously from a low temperature object to a higher temperature object.
Tell me, what is strange and bizarre about my stating the Second Law and saying that I believe it to not only be true, but to mean what it says? What is bizarre Ian, is claiming that it doesn't mean what it says when if science had found it to be proveably wrong then science would have recended it and replace it with a more accurate statement. If the law didn't apply to individual events, and that was a proveable fact, don't you think that qualifier might be inclued in the statement of the law?
Would you think it bizarre if I quoted the Ideal Gas Law in a discussion over whether or not the state of a gas is determined by its pressure, volume and temperature?
Would you accuse me of bizarre theories if I quoted Dalton's Law if we were in disagreement over whether the pressure of a mixture of gasses is equal to the sum of the partial pressures of the component gasses and said that you were wrong if your position were in opposition to the statement of that law?
If you would think that bringing the statements of those laws into those conversations would constitued bizarre beliefs on the part of the one who used them, then you are even further out there than I had suspected....now if the use of those physical laws, in support of an argument are not bizarre, how then could the use of the statement of the most fundamental physical law be any more bizarre? What is bizarre Ian, is to be in disagreement with that statement.
So you keep saying but all I need do is quote the Second Law and ask you how it applies to the greenhouse effect hypotheisis, and you immediately deviate from the statement of the law and go into how it doesn't really mean what it says or that even though it is written in absolute terms it doesn't really mean what it says. If you disagree with it as an absolute statement regarding the movement of energy from one place to another, then you, by definition, think it is wrong.
And that is what it remains. Till some actual evidence, beyond mathematical and computer models proves it wrong, it is what it is. You are trying to replace a law of nature with a theory...it is as simple as that. QM is theoretical and will remain theoretical for longer than either of us have left on this earth and much of what it states today will be found out to be completely wrong. Any thoery that must form an ad hoc solution to explain the orbitals of a hydrogen atom is suspect from the start.
Statistical mechanics is a theory and it ATTEMPTS TO DESCRIBE. There is a fundamental difference between describing a thing not understood in factual, proveable terms and attempting to describe a thing not understood in unproven theoretical ideas. You put far to much faith in things that aren't even beginning to be proven.
but nowhere in all the volumes that have been writen about thermodynamics is there anything stating the existence of a previously unknown physical law prohibiting radiation emission from a particle, or the emission in a certain direction, because of a temperature differential. you wont even say how the particle knows the temperature of its surroundings.
There doesn't need to be any such statement for reasons I have already given you. The statement of the Second Law is made in absolute terms.
It is not possible for heat to flow from a colder body to a warmer body without any work having been done to accomplish this flow. Energy will not flow spontaneously from a low temperature object to a higher temperature object. A statement like that doesn't need further qualification. There is no need to describe every possible energy exchange from place to place or in quanity.
The statement says that it is not possible for heat to flow from a colder body to a warmer body. Which part of "not possible" is it that you are having problems understanding. A statement like that makes it unnecessary to describe when heat might flow from a cooler object to a warmer object because it is "NOT POSSIBLE". If it were possible, then the statement would say something else, or not exist at all.
"ENERGY WILL NOT FLOW SPONTANEOUSLY FROM A LOW TEMPERATURE OBJECT TO A HIGHER TEMPERATURE OBJECT". That statement does not need a sub statement saying that the law also includes particles. It says that energy WILL NOT flow from a low temperature object to a higher temperature object. The law would fill volumes that would fill and overflow the library of congress if it were necessary to clearly state every possible energy exchange.
The statement is that it is NOT POSSIBLE for heat to flow from a colder body to a warmer body and energy WILL NOT flow spontaneously from a low temperature object to a higher temperature object and it is enough. If you have a theory or hypothesis that runs afoul of that statement, then your theory or hypothesis is doomed no matter how much press it can get and you will, in fact, be the one guilty of bizarre behavior in trying to get around the most fundamental law of nature.