IanC said:
Two objects of the same temperature, not touching and in a vacuum (no conduction or convection). Do they radiate at each other? If they do I am right ( or at least more correct). If they don't what happened to the radiation and how did the objects know the other was there and what temperature it was at?
I didn't feel like searching throug the thread to figure out the entire context. The original point may have gotten lost, but I think I got the gist of it, which is why I posted;
"Thermodynamics is a description of net averages. It is not a description of individual particles. The difference can be seen in the random walk of Brownian motion. Refer to Einstien's paper on Brownian Motion, in which he tied the laws of thermodynamics to elementary particles, proved the existence of atoms and molecules as real objects, and demonstrated that the laws of thermodynamics describe the statistical average behavior of large quantities of particles."
You are absolutely correct. *Two systems at thermal disequilibrium do transfer instantaneous energy in both directions. Thermodynamic laws are a description of the statistcal averages for large numbers of particle.
As your example implies, two bodies at different temperatures emit radiation completely independent of each other. The body at a higher temperature does absorb energy from the cooler body. The warmer body, on average, emits more radiation than the cooler body. So, on average, there is a net energy transfer from the warmer to the cooler body.
In terms of gasses and other matter, where the energy is tranfered in the form of kinetic energy, it was not resolved, until Einstein's paper on Brownian motion, if atoms and molecules were a real or theoretical construct. *Einstein showed them to be real and the issue of thermodynamic laws being a statistical macro process was resolved.
It now comes down to probabilities. It is statistically, and really possible, for the net energy movement to be transfered from the cold body to the warm one. *In practice, over large quantities of particles, the probability of this occuring is so increadibly small, as to make it insignificant in practice. In practice, it is practically impossible. It is not absolutely impossible. And there is no way to utilize this to extract energy from the system or violate the macro laws of thermodynamics. *Any device imaginable is part of the thermodynamic system and, as such, cannot change the macroscopic outcome.