Bullshit. CO2 residence time is between 5 and 16 years.
Essenhigh (2009) points out that the IPCC (Intergovernmental Panel on Climate Change) in their first report (Houghton et al., 1990) gives an atmospheric CO2 residence time (lifetime) of 50-200 years [as a "rough estimate"]. This estimate is confusingly given as an adjustment time for a scenario with a given anthropogenic CO2 input, and ignores natural (sea and vegetation) CO2 flux rates. Such estimates are analytically invalid; and they are in conflict with the more correct explanation given elsewhere in the same IPCC report: "This means that on average it takes only a few years before a CO2 molecule in the atmosphere is taken up by plants or dissolved in the ocean".
Some 99% of the atmospheric CO2 molecules are 12CO2 molecules containing the stable isotope 12C (Segalstad, 1982). To calculate the RT of the bulk atmospheric CO2 molecule 12CO2, Essenhigh (2009) uses the IPCC data of 1990 with a total mass of carbon of 750 gigatons in the atmospheric CO2 and a natural input/output exchange rate of 150 gigatons of carbon per year (Houghton et al., 1990).
The characteristic decay time (denoted by the Greek letter tau) is simply the former value divided by the latter value: 750 / 150 = 5 years. This is a similar value to the ~5 years found from 13C/12C carbon isotope mass balance calculations of measured atmospheric CO2 13C/12C carbon isotope data by Segalstad (1992); the ~5 years obtained from CO2 solubility data by Murray (1992); and the ~5 years derived from CO2 chemical kinetic data by Stumm & Morgan (1970).
Revelle & Suess (1957) calculated from data for the trace atmospheric molecule 14CO2, containing the radioactive isotope14C, that the amount of atmospheric "CO2 derived from industrial fuel combustion" would be only 1.2% for an atmospheric CO2 lifetime of 5 years, and 1.73% for a CO2 lifetime of 7 years (Segalstad, 1998). Essenhigh (2009) reviews measurements of 14C from 1963 up to 1995, and finds that the RT of atmospheric 14CO2 is ~16 (16.3) years. He also uses the 14C data to find that the time value (exchange time) for variation of the concentration difference between the northern and southern hemispheres is ~2 (2.2) years for atmospheric 14CO2. This result compares well with the observed hemispheric transport of volcanic debris leading to "the year without a summer" in 1816 in the northern hemisphere after the 1815 Tambora volcano cataclysmic eruption in Indonesia in 1815.
Sundquist (1985) compiled a large number of measured RTs of CO2 found by different methods. The list, containing RTs for both 12CO2 and 14CO2, was expanded by Segalstad (1998), showing a total range for all reported RTs from 1 to 15 years, with most RT values ranging from 5 to 15 years. Essenhigh (2009) emphasizes that this list of measured values of RT compares well with his calculated RT of 5 years (atmospheric bulk 12CO2) and ~16 years (atmospheric trace 14CO2). Furthermore he points out that the annual oscillations in the measured atmospheric CO2 levels would be impossible without a short atmospheric residence time for the CO2 molecules.
Essenhigh (2009) suggests that the difference in atmospheric CO2 residence times between the gaseous molecules 12CO2 and 14CO2 may be due to differences in the kinetic absorption and/or dissolution rates of the two different gas molecules.
With such short residence times for atmospheric CO2, Essenhigh (2009) correctly points out that it is impossible for the anthropogenic combustion supply of CO2 to cause the given rise in atmospheric CO2. Consequently, a rising atmospheric CO2 concentration must be natural. This conclusion accords with measurements of 13C/12C carbon isotopes in atmospheric CO2, which show a maximum of 4% anthropogenic CO2 in the atmosphere (including any biogenic CO2), with 96% of the atmospheric CO2 being isotopically indistinguishable from "natural" inorganic CO2 exchanged with and degassed from the ocean, and degassed from volcanoes and the Earth's interior (Segalstad, 1992).
Essenhigh, R.E. 2009: Potential dependence of global warming on the residence time (RT) in the atmosphere of anthropogenically sourced carbon dioxide. Energy & Fuels 23: 2773-2784.
Houghton, J.T., Jenkins, G.J. & Ephraums, J.J. (Eds.) 1990: Climate Change. The IPCC Scientific Assessment. Intergovernmental Panel on Climate Change. Cambridge University Press, Cambridge: 365 pp.
Murray, J.W. 1992: The oceans. In: Butcher, S.S., Charlson, R.J., Orians, G.H. & Wolfe, G.V. (Eds.): Global biogeochemical cycles. Academic Press: 175-211.
Revelle, R. & Suess, H. 1957: Carbon dioxide exchange between atmosphere and ocean and the question of an increase of atmospheric CO2 during past decades. Tellus 9: 18-27.
Segalstad, T. V. 1982: Stable Isotope Analysis. In: Stable Isotopes in Hydrocarbon Exploration, Norwegian Petroleum Society 6904, Stavanger: 21 pp. Available at:
http://www.co2web.info/STABIS-ANAL.pdf
Segalstad, T. V. 1992: The amount of non-fossil-fuel CO2 in the atmosphere. AGU Chapman Conference on Climate, Volcanism, and Global Change. March 23-27, 1992. Hilo, Hawaii. Abstracts: 25; and poster: 10 pp. Available at:
http://www.co2web.info/hawaii.pdf
Segalstad, T. V. 1996: The distribution of CO2 between atmosphere, hydrosphere, and lithosphere; minimal influence from anthropogenic CO2 on the global "Greenhouse Effect". In Emsley, J. (Ed.): The Global Warming Debate. The Report of the European Science and Environment Forum. Bourne Press Ltd., Bournemouth, Dorset, U.K. [ISBN 0952773406]: 41-50. Available at:
http://www.co2web.info/ESEFVO1.pdf
Segalstad, T. V. 1998: Carbon cycle modelling and the residence time of natural and anthropogenic atmospheric CO2: on the construction of the "Greenhouse Effect Global Warming" dogma. In: Bate, R. (Ed.): Global warming: the continuing debate. ESEF, Cambridge, U.K. [ISBN 0952773422]: 184-219. Available at:
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