SSDD has as much problems collecting inferred knowledge from graphs as Crick does.
Satellites measuring outgoing radiation from the earth 'see' CO2 specific radiation coming from a source that appears to be -80C. So what does that mean?
It means that CO2 specific radiation cannot pass through the atmosphere and escape to space until it reaches a height in the atmosphere where the density of the air is so thin that it is no longer likely to absorb that radiation. How high? The layer that corresponds to -80C. (Yes I know it is a fuzzy boundary)
Until that point any radiation emitted by CO2 is retained by the atmosphere, the Greenhouse Effect.
The so-called Atmospheric Window allows radiation around 10 microns to escape directly to space. This radiation is not part of the Greenhouse Effect. Where do the satellites 'see' this radiation coming from? The layer coming from a temperature of +15C, the surface.
And "retained by the atmosphere" you mean that the excited CO2 is hotter than it's non-excited neighbor?
I am pretty sure we have been through this numerous times.
It takes a lot of stored energy to keep an atmosphere aloft in the gravity field and at its temperature. These two things are interconnected. The first is potential energy, and the second is kinetic energy. You do realize that the kinetic energy portion, the speed of the molecules is what defines the temperature? Every collision rearranges the proportion of kinetic to potential energy.
Next, we have to decide whether molecules absorbing photons is potential or kinetic energy. Either an electron is bumped into a higher energy orbital or the bonds between the constituent elements is changed in fashion that is called vibration. Neither of these changes the speed of the molecules, so it obviously is a change of potential energy.
To be more complete, there is also an exchange of momentum between the emitters and absorbers. A tiny fraction which drives the two away from each other, and ensures that entropy ensues.
In a collision the two (or more) molecules crash together and the potential and kinetic energies are briefly combined by deforming the electron shells. When they move apart the combined energy is once again divided up into potential and kinetic energies. The individual molecule may have more or less of each upon leaving. An excited molecule may return to ground state at a different speed, or a ground state molecule may exit in an excited state. There are numerous possibilities. These collisions also cause blackbody radiation to be formed. Higher energy photons from high speed head on collisions, lower energy photons from glancing or low speed collisions.
To reiterate, a CO2 molecule that absorbs a photon simply adds to the total energy of the atmosphere, part of which is in kinetic energy AKA temperature.
This also makes it easier to understand why, at higher altitude where it is less dense hense fewer collisions , that CO2 molecules can hold onto the excited state long enough to emit a photon that won't simply be recaptured.