http://www.geos.ed.ac.uk/~dstevens/Presentations/Papers/stevenson_gssp03.pdf
Sulphur occurs in EarthÂ’s atmosphere as a variety of compounds, in both gaseous and
aerosol forms, and has a range of natural and anthropogenic sources. The life cycles and
atmospheric burdens of these compounds are determined by a combination of physical,
chemical and biological processes. Understanding the global S-cycle is important for
many reasons. Most sulphur enters the atmosphere as gaseous sulphur dioxide (SO2), a
dangerous air pollutant. Sulphur dioxide has a lifetime in the atmosphere of about a day,
before being deposited to the surface or oxidised to sulphate (SO4) aerosol. In the gas
phase, SO2 oxidation occurs by reaction with hydroxyl radicals (OH), to form sulphuric
acid (H2SO4). Sulphuric acid is hygroscopic, and rapidly condenses, either forming new
aerosols, or adding to existing ones. Sulphur dioxide gas also partitions into the aqueous
phase (in cloud droplets or pre-existing aerosols), where it reacts with dissolved hydrogen
peroxide (H2O2) or ozone (O3) to form SO4. Sulphate is a major component of fine
aerosol particles (PM10 and PM2.5: particulate matter less than 10 mm or 2.5 mm in
diameter), which can penetrate deep into the lungs, and are harmful to health. Sulphate in
precipitation is an important determinant of its acidity; at high levels it causes ‘acid rain’,
which can have devastating effects on sensitive ecosystems. Sulphate aerosols also affect
EarthÂ’s radiation balance (and hence climate) through the direct scattering of sunlight
(Charlson et al., 1992), and also indirectly via modification of cloud albedoes (Twomey,
1977) and lifetimes (Jones et al., 2001), influencing both radiation and the hydrological
cycle (Penner et al., 2001). These links between atmospheric sulphur, climate, and the
environment assume an even greater relevance
since global anthropogenic emissions (60-
100 Mt(S) yr-1) currently account for about 70% of all sulphur emissions, the remainder
emanating from oceanic plankton (13-36 Mt(S) yr-1), volcanoes (6-20 Mt(S) yr-1),
biomass burning (1-6 Mt(S) yr-1), and land biota and soils (0.4-5.6 Mt(S) yr-1) (Penner et
al., 2001). On a regional scale, and in particular over N.E. America, Europe, and S.E.
Asia, the anthropogenic fraction is much higher.
This seems to be a pretty definitive article on the sources of SO2 and other sulpher compounds in the atmosphere, and there effects on humans.