The absorption of a photon or involvement in an molecular collision increase the energy state of that molecule or atom instantly. That increase is expressed kinetically as heat, instantly. Same Shit's claim that CO2 can absorb photons without increasing temperature is absolute nonsense. He seems to think that atoms put photons out in the woodshed and wait for a cold day before throwing them on the fire. When an atom or molecule absorbs a photon, it instantly increases in temperature. If it reemits that photon a nanosecond later, than it decreases in temperature that nanosecond later. It is akin to their idea that energy absorbed at shallow depths in the oceans surface can't find its way deeper. You see this a lot with SSDD and Westwall (and Billy Boy with zettajoules), that they seem to think the universe is restricted to operating in the range scales they personally find comfortable.
Throw a ball straight up in the air. Let's say you give it a velocity at release of 32 feet/second. From the instant you release it, you no longer have any ability to affect its speed. It is now subject to gravity and air resistance, which we shall ignore. The force of gravity, of course, is downward. The result of the application of a force on a mass is the acceleration of that mass. Although initially the ball is traveling upward, it is accelerating downward. We use the word decelerate for a state of acceleration in opposition to motion. The ball will accelerate at -32 ft / second / second (or -32 ft/sec^2 (or -32 ft sec^-2)) constantly, from the instant you release it till the instant it strikes the ground, regardless of it's velocity (ie motion in a direction) over that period. Over the first second, the ball will decelerate from 32 ft / second to a speed of 0. For the next second and a little bit longer (depending how tall you are*) it will accelerate and strike the ground at something a little over the 32 ft / second at which you threw it.
The difference between an Earth with no greenhouse gases and the one we have is that a significant portion of the thermal energy developed in the Earth's surface by the direct absorption of solar radiation, then reemitted upward, is absorbed by water vapor, CO2, CH4 and other greenhouse gases. On a planet with no greenhouse gases, that energy is transmitted at the speed of light into space. None of it stays and warms the atmosphere. None of it finds it way back down to the surface. The difference between the two is 33 centigrade degrees (59.4F)
* At 2 seconds, the ball is back at the height at which you released it when you threw. It still has to travel a little further to reach the ground. During that time it will be accelerating at the same 32 ft sec^-2