So I am actually trying to keep an open mind your axiom that an electromagnetic emission from a vibrating matter particle can’t hit another particle with higher kinetic energy. And from my interpretation, thermal radiation behaving like this could still contribute to decreasing the rate of global cooling, and here’s why:
Matter density exists on a continuum, perfect vacuums are rare on and surrounding earth. So from the surface of earth on up to extremely high altitudes, the thermal radiation rules for “in the presence of other matter” should apply. Now we know the major input to the system is thermal radiation from the sun. The land surface of earth will absorb much of that, and also water molecules under many conditions. I think you’ve also said that CO2 will absorb and then re-emit thermal radiation. Under the conditions I’ve outlined above, who’s to say it has to always re-emit it directly into space? It could just “target” a cooler CO2 or H2O molecule, right? As long as radiation is bouncing around on earth and the atmosphere, it’s not escaping as fast as it would without the atmosphere.
You haven't been around SSDD as much as the others on this board, so you may not realize that he pretends science is different than what it is so he can practice a sort of a "flat-earth" type of dialog. He has been backed into a corner on many of his pretended "beliefs". He believes that at thermal equilibrium two objects at the same temperature do not radiate anything toward each other. In one single post he has referred in derogatory terms to those who believe in exchanged radiation in thermal equilibrium as:
"using shitty math"
"attempt to fool idiots"
"bullshit equation"
"piss poor mathematical skills"
"senseless rants"
"are a dupe"
That rant would also defame, Albert Einstein, Wilhellm Wein Gustav Kirchhoff, Max Plank, Niels Bohr, who are all Nobel Prize winners. He is also defaming all scientists for the last 100 years or so.
He is full of bluff, bluster, and argumentum ad hominem. Don't expect much science dialog. But it is an interesting game watching him try to squirm out of real science with outlandish pretenses.