Phd geologist? The proxies indicate strong rise in GHGs before both the PT event and the Tertiary event.
The Permian-Triassic Extinction - Volcanism and the Great Dying
Consider the stressed biosphere late in the Permian: low oxygen levels restricted land life to low elevations. Ocean circulation was sluggish, raising the risk of anoxia. And the continents sat in a single mass (Pangea) with a reduced diversity of habitats. Then great eruptions begin in what is Siberia today, starting the largest of Earth's large igneous provinces (LIPs).
These eruptions release huge amounts of carbon dioxide (CO2) and sulfur gases (SOx). In the short term the SOx cools the Earth while in the longer term the CO2 warms it. The SOx also creates acid rain while CO2 entering the seawater makes it harder for calcified species to build shells. Other volcanic gases destroy the ozone layer. And finally, magma rising through coal beds releases methane, another greenhouse gas.
With all of this happening to a vulnerable world, most life on Earth could not survive. Luckily it has never been quite this bad since then. But global warming poses some of the same threats today
I prefer this discussion on the extinction event. It has no internal bias. Climate change is addressed and cold comes out as a possible cause by a margin of four to one against warming as a cause. Further the largest sea level drop ever recorded occurred at the end of the Permian further reinforcing the theory that it was glaciation that was a proximal cause of extinction.
Palaeobiology and Biodiversity Research Group, Department of Earth Sciences, University of Bristol
Palaeobiology and Biodiversity Research Group, Department of Earth Sciences, University of Bristol
Isotopes and climate
Isotopes across the PTB and climate change
A major objective on the 2004 expedition was to take samples for isotopic analysis. The key isotopes are those of oxygen and carbon. At the PTB, there is a dramatic shift in oxygen isotope values of marine carbonates,
a decrease in the value of the δ18O ratio of about six parts per thousand (ppt), corresponding to a global temperature rise of about 6oC. Climate modellers have shown how global warming can reduce ocean circulation and the amount of dissolved oxygen, creating anoxia in the oceans; this is seen in marine sediments from around the world. The marine evidence for anoxia nearly world-wide is dramatic and convincing, and this episode of superanoxia, which surely killed much of the life on the sea bottom (Wignall & Twitchett, 1996), must form part of any model for events at the PTB.
Carbon isotopes have been hugely important in determining models for the PT mass extinction. Geochemists measure the ratio of the stable isotopes 13C and 12C in limestones and fossil shells, and even in carbonate palaeosols. In nature, most carbon occurs as 12C, with minor, but measurable, amounts of 13C. The ratio of these two isotopes in the atmosphere is the same as in the surface waters of the oceans. During photosynthesis, plants preferentially take up 12C to produce organic matter. If this organic matter is buried, rather than returned to the atmosphere-ocean system, then the atmosphere-ocean 13C: 12C ratio will shift in favour of the heavier isotope. Conventionally, this ratio is expressed as δ13C, which is the difference between the 13C: 12C ratios in the sample being tested and in a known standard.
In the ocean system, during times of high surface productivity, large amounts of organic matter are fixed at the surface and the surface waters of the ocean become (relatively) enriched in 13C. Shallow-water carbonate deposits are precipitated from this seawater, and record the seawater 13C: 12C ratio without any preferential uptake of one or other isotope. Therefore, during times of high surface productivity, shallow water carbonates record a positive shift in δ13C (i.e. towards the heavier isotope).
The PTB is characterized by a negative shift in δ13C, which is recorded in the carbonate deposits of all geological sections studied so far (e.g. Magaritz et al. 1988; Sephton et al., 2002), including terrestrial ones (Retallack 1995; MacLeod et al. 2000). On the face of it, this should imply a massive decrease in biological production and rate of burial of organic matter.