JimBowie1958
Old Fogey
- Sep 25, 2011
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http://phys.org/news/2012-05-nanosheet-catalyst-sustainably-hydrogen.htm
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Nanotech is changing and improving our lives in ways no one even imagined ten years ago. The future is bright for humanity if we can just not kill each other off.
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Now, scientists at the U.S. Department of Energy's (DOE) Brookhaven
National Laboratory have developed a new electrocatalyst that addresses
one of these problems by generating hydrogen gas from water cleanly and
with much more affordable materials. The novel form of catalytic
nickel-molybdenum-nitride - described in a paper published online May 8,
2012 in the journal Angewandte Chemie International Edition - surprised
scientists with its high-performing nanosheet structure, introducing a
new model for effective hydrogen catalysis.
"We wanted to design an optimal catalyst with high activity and low
costs that could generate hydrogen as a high-density, clean energy
source," said Brookhaven Lab chemist Kotaro Sasaki, who first conceived
the idea for this research. "We discovered this exciting compound that
actually outperformed our expectations."
Goldilocks chemistry
Water provides an ideal source of pure hydrogen - abundant and free of
harmful greenhouse gas byproducts. The electrolysis of water, or
splitting water (H2O) into oxygen (O2) and hydrogen (H2), requires
external electricity and an efficient catalyst to break chemical bonds
while shifting around protons and electrons. To justify the effort, the
amount of energy put into the reaction must be as small as possible
while still exceeding the minimum required by thermodynamics, a figure
associated with what is called overpotential.
Nanotech is changing and improving our lives in ways no one even imagined ten years ago. The future is bright for humanity if we can just not kill each other off.