I am continuing my research in this forum section because in the thread "Does God exist" in the religion section too many other subjects are being discussed and few are addressing the need for different environments to produce different amino acids.
The lack of the chemical reaction product proportions in the famous Miller-Urey experiment is typical - thankfully not universal. Some of the details are found in tables 3-2, 3-3. 3-4 and 3-5 on pages 23-29 of:
Note that the most abundant chemical reaction product in the spark discharge experiments is formic acid not amino acids. And that most of the amino acids produced (exceptions: Glycine, Alanine and in lower proportion Aspartic Acid) are not found in proteins.
The reason for the predominance of formic acid is that these experiments are done in the presence of water with a theorized atmosphere of methane (CH4), ammonia (NH3) and hydrogen (H2) which produces hydrogen cyanide (HCN). Hydrolysis is the adding of water (H2O) to a molecule. In the case of HCN:
HCN + H2O yields formamide + H2O yields formic acid.
The hydrolysis of HCN is largely ignored in peer reviewed journals discussing amino acid synthesis. Actually, hydrolysis stops many chemical reaction pathways involving HCN and on to proteins. In fact, popular reports deceive people into thinking water is required whereas water is really an enemy of amino acid synthesis and polymerization.
Thaxton et al note some of the many hydrolysis reactions that dead end pathways to amino acids on page 50. These include: [see the article for structure e.g. bonding type and shape]
1. HCN to Cyanogen (C2N2) +H2O yields cyanoformamide (C2H2N2O) + H2O yields ethanediamide (C2H4N2O2)
2. HCN to dicyanamide (C2N3) + H2O yields cyanourea (C2H3N3O) + H2O yields Biuret (C2H5N3O2 )
3. HCN to Cyanamide (CH2N2) + H2O yields Urea (CO(NH2)2 = CH4N2O = NH2CONH2)
4. HCN to Cyanamide (CH2N2) + H2O yields carbodiimide (RN=C=NR.) + H2O yields Urea
[Note: The carbodiimide dicyclohexylcarbodiimide (C13H22N2 ) is used in peptide synthesis,"]
5. HCN + H2O yields formamide (CH3NO) + H2O yields formic acid (HCOOH = CHâ‚‚Oâ‚‚)
6. HCN + H2O yields formamidine (CH4N2 ) + H2O yields formic acid
7. HCN to Cyanoacetylene (C3HN) + H2O yields Cyanoacetaldehide (C3H3NO).
You all- feel free to post anything concerning amino acids synthesis or to respond concerning any chemical reaction I posted above.
The lack of the chemical reaction product proportions in the famous Miller-Urey experiment is typical - thankfully not universal. Some of the details are found in tables 3-2, 3-3. 3-4 and 3-5 on pages 23-29 of:
Note that the most abundant chemical reaction product in the spark discharge experiments is formic acid not amino acids. And that most of the amino acids produced (exceptions: Glycine, Alanine and in lower proportion Aspartic Acid) are not found in proteins.
The reason for the predominance of formic acid is that these experiments are done in the presence of water with a theorized atmosphere of methane (CH4), ammonia (NH3) and hydrogen (H2) which produces hydrogen cyanide (HCN). Hydrolysis is the adding of water (H2O) to a molecule. In the case of HCN:
HCN + H2O yields formamide + H2O yields formic acid.
The hydrolysis of HCN is largely ignored in peer reviewed journals discussing amino acid synthesis. Actually, hydrolysis stops many chemical reaction pathways involving HCN and on to proteins. In fact, popular reports deceive people into thinking water is required whereas water is really an enemy of amino acid synthesis and polymerization.
Thaxton et al note some of the many hydrolysis reactions that dead end pathways to amino acids on page 50. These include: [see the article for structure e.g. bonding type and shape]
1. HCN to Cyanogen (C2N2) +H2O yields cyanoformamide (C2H2N2O) + H2O yields ethanediamide (C2H4N2O2)
2. HCN to dicyanamide (C2N3) + H2O yields cyanourea (C2H3N3O) + H2O yields Biuret (C2H5N3O2 )
3. HCN to Cyanamide (CH2N2) + H2O yields Urea (CO(NH2)2 = CH4N2O = NH2CONH2)
4. HCN to Cyanamide (CH2N2) + H2O yields carbodiimide (RN=C=NR.) + H2O yields Urea
[Note: The carbodiimide dicyclohexylcarbodiimide (C13H22N2 ) is used in peptide synthesis,"]
5. HCN + H2O yields formamide (CH3NO) + H2O yields formic acid (HCOOH = CHâ‚‚Oâ‚‚)
6. HCN + H2O yields formamidine (CH4N2 ) + H2O yields formic acid
7. HCN to Cyanoacetylene (C3HN) + H2O yields Cyanoacetaldehide (C3H3NO).
You all- feel free to post anything concerning amino acids synthesis or to respond concerning any chemical reaction I posted above.
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