This is why we all disagree with SSDD. He asserts that the SLoT applies to all energy transfers right down to the atomic level, rather than just a statistical description of large numbers of interactions.
I read through a lot of this thread but could find no reason why he could come conceivably think that way. He seems to know physics and thermodynamic terminology but comes to conclusions that are well beyond the norms of physics.
I haven't read all of this thread but I have debated SSDD many times in the past. He comes from the 'Slayers' camp.
They distort the definitions of physics to 'prove' that CO2 can have no impact on heat transfer. They just repeat their talking points and refuse to answer embarrassing questions. Google Spencer's 'Yes Virginia' or Willis's 'Shell' to see what I mean. In a way it is good because it sharpens your thinking to refute their points.
I dont think that it is an intentional distortion. IF we simply change basic items in question, which science has not quantified, the position becomes very possible. CO2 has little to do with increasing heat transfer but has everything to do with slowing that same process. It is the slowing of the process in earths atmosphere that is the sticking point for most of us. SSDD's main point, as i understand it, is the convection cycle of our earth is such that CO2 has little or no impact on the rate we warm. IF we were just a CO2 based atmosphere then the LOG formula would rule, but we are a water based atmosphere and it is not restrained by that rate of diminishing return.
The problem with the IPCC and many other theories, is they do not take into consideration that convection cycle. A slight thinning of the atmosphere by CO2 can act as a lubricant or friction reducing property. This is precisely what we are seeing with TOA measurements and LWIR release increase. The proportional increases are linear, suggesting that CO2 is actually increasing the rate of cooling by a secondary and unexpected effect.
IT will take some time to prove or disprove this observations causation.