the 2nd law states that there can be no net flow of heat from colder to warmer.
ian, the second law of thermodynamics says no such thing. I have posted it for you numerous times and there is nothing whatsoever there about "net" energy flow. Again, here is the 2nd law of thermodynamics:
"It is not possible for heat to flow from a colder body to a warmer body without any work having been done to accomplish this flow. Energy will not flow spontaneously from a low temperature object to a higher temperature object. "
"Second Law of Thermodynamics: It is
not possible for heat to flow from a colder body to a warmer body without any work having been done to accomplish this flow. Energy will
not flow spontaneously from a low temperature object to a higher temperature object. "
So tell me ian, where do you see anything there about "net" energy flow? You don't. The second law doesn't say anything about "net" energy flow but somewhere along the way, you have bought a bill of goods so thoroughly that you can apparently look at the statement above and see the word "net" in there somewhere. The idea of "net" energy flow is in all likelyhood an artifact that resulted from the corruption of the Stefan-Boltzman law which you have also bought into. The argument in support of backradiation is circular in nature ian, sorry that you can't see it.
The idea of backradiation is supported by the corrupted version of the SB law which is supported by a corrupted statment on the 2ndl law of thermodynamics which the corrupted SB law introduces. You have bought into pseudoscience ian, not actual science. The second law of thermodynamics as stated above is science and I am sorry to tell you, but it doesn't support your view of the physical universe.
the cancelling out of radiation flow going in both directions is a mathematical calculation, not a physical obliteration of photons. and it certainly doesnt happen without the presence of matter.
Again ian, sorry that your very immature view of physics doesn't allow you to see what is actually happening. The cancelling out of radiation flow via the subtraction of EM fields is a very real phenomenon that is calculated, and put into actual physical practice by electrical engineers every day. Your view of the behavior of photons, on the other hand, is really nothing more than a mathematical artifiact and the result of a corruption of one of the laws of physics to boot.
you have put up zero evidence of this magical destructions of photons. you wont even pinpoint where this is supposed to happen. I have asked you dozens of times whether it happens at the surface, CO2 molecule or just in space but you refuse to give an answer.
Because it isn't magical ian. Apparently it is so far over your head (which is sad) that it only appears to be magic to you. When you subtract EM fields ian, what do you suppose you are subtracting? When the magnitude of an EM field diminishes, what do you suppose it has lost in order for it to be diminished? In order for you to grasp this ian, you are going to have to embrace particle-wave duality and until you do, this is going to look like magic to you and you are going to continue to misunderstand.
the closest I have come to finding something that supports your view is Claes Johnson's discussion on how he thinks the back radiation is reversed at the surface, much like reflection. no cancelling out, and the 'resonated reemission' is part of the radiation calculated for the earth's surface, not some extra bit. this calculation works out to exactly the same numbers as the 'corrupted version' of the S-B formula.
Johnson says no such thing. Again, your immature view of photons can not be applied to reality. Till you accept particle-wave duality, this will continue to escape you. As to the answer being the same with the corrupted version of the SB law, again, you fail to see the issue. The corrupted version of the SB law describes a physical process that is not happening. It describes a violation of the 2nd law of thermodynamics in order to support a non physical phenomenon which allows a corruption of the 2nd law of thermodynamics all for the purpose of promoting AGW alarmism.
Without backradiation, there is no AGW alarmism. Without corruptig the SB law, there can be no support of backradiation which in turn allows you to claim that the 2nd law of thermodynamics is describing net flows which, in reality, it is not.
It is unfortunate that the level of public education has dipped to the level that allows so many people to be taken in by that very bit of sleight of hand ian; and not just you, but scientists who should know better and whole generations are being taught that very bit of rubbish as if it were true.
one of the biggest problems in physics is being able to resolve what happens on a micro scale to the reality of the macro scale.
Your biggest problem with regard to what is happening here is your inability to understand and grasp wave particle duality. Till you get that ian, this will continue to go right over your head. Phenomena like EM interference, and cancellation can only be explained by looking at EM fields as waves. The phenomena are real and measurable, but not explainable if you assume EM fields are made up of discrete particles. Your thinking along this line is very immature and as a result, to rigid for you to actually grasp what is going on. You are stuck with particles and particles don't explain what is happening.
you are trying to switch back and forth from large to small scale.
No I am not ian, I have a grasp of particle wave duality and therefore am not confined within your small mental box trying to apply particle physics to a physical phenomenon that particle physics can not, and does not try to explain.
heat flow only goes in one direction but radiation flow goes in both.
Radiation can go in both directions if the frequencies are different, but we aren't talking about different frequencies. The frequency of IR changes as it passes through a CO2 molecule but it does not change enough to get outside of the broad band of IR being emitted by the surface of the earth. Cancellation, interference, and subtraction of EM fields is a very real, observable phenomenon ian and it can't be explained rationally by viewing EM fields as being made up of discrete particles. You have to look at EM fields as waves in order to explain what is happening in the real world. Your thinking isn't mature enough for that at this point so you are left calling it magic.
an excited molecule doesnt check to see if it is allowed to emit energy by radiation, it just emits. the photon doesnt care which direction it is heading in, it just goes. the photon doesnt care whether it has enough energy to warm a body or just cancel out radiation in the other direction leading to a 'net flow'. CO2 doesnt care if it is a good emitter and absorber at certain wavelengths and a poor one at others, it just is what it is regardless.
Yes, it just goes ian, but it goes in the direction of propagation of the EM field which has the larger magnitude. If it is in opposition to that field, it is expended (subtracted). Again, when you subtract EM fields, what do you think you are subtracting? The explanation on spencer's page by gord was ok. The block of wood being pushed on in two directions doesn't know, or care which direction it is supposed to go. It just moves in the direction of greater force. The photon can not move in a direction opposite to the direction from which the EM field with the larger magnitude was propagated.
do I like the surface radiation and atmospheric back radiation components in Trenberth's diagram? no, I think it should just show ~60W/m2 going up, perhaps with a side diagram showing the the calculation of radiation in both directions. do I think Trenberth has the right figures for the energy coming in and going out? I dont think it is exactly right but it is probably reasonably close.
At this point ian, I really don't care what you like and don't like and don't even take such things in consideration because you have demonstrated beyond even the smallest reasonable doubt that you simply don't get it. This whole subject is beyond you and as a result, you are operating from a position of faith, not any inherent knoledge. When you do bring bits of science forward in an attempt to support your position, it is clear that you don't understand what you are saying.
Until there is proof that that explanation is wrong, and accepted by more than a few fringe crackpots, I will continue to believe that CO2 is a factor in atmospheric processes but I will also continue to be sceptical of the high feedback values which lead to global warming alarmism.
There is proof that the explanation is wrong and hard, repeatable, observable proof that backradiation from the atmosphere to the surface of the earth does not exist. You can prove it yourself in your own back yard. I have done it in my back yard. If you would like plans for the experiment, I will gladly provide them to you.
You make a parabolic dish and point it into the sky on a sunny day. If you point it at the sun, you get a great deal of heat very quickly. But if you point it towards clear sky, even on a bright sunny day, the temperature at the bottom of the dish drops below the abient temperature. If backradiation were "beaming"back down to the surface of the earth and warming the surface, then there is no physical way the temperature in that dish could drop below the ambient temperature. The dish is behaving precisely as the second law of thermodynamics predicts. Heat is flowing from warm to cool and nothing is moving in the opposite direction. At night, you can cause ice to form in that dish if the ambient temperature is around 45 degrees. Even lower if the humidity is lower.
There is hard, observable, repeatable evidence that the claim of backradiation is wrong ian but like the scientists who have a financial stake in AGW alarmism, my bet is that you wll ignore what you can see in favor of faith.
wirebender, care to explain where and how all these photons magically disappear? in the real world and not in some calculation?
First, there is no magic. It only appears to be magic to you because it is beyond your understanding. Do you deny that EM fields interfere with, and cancel each other out and this phenomenon is measurable? If you do, then you are well and truely full of BS. Since the phenomenon of cancellation and interference happens, and one EM field can be reduced in magnitude by another and can be measured, what do you suppose is being subtracted? The answer is photons ian. It looks like magic to you because your thinking hasn't matured to encompass particle wave duality. The answer lies there and till you can grasp it, this will remain over your head.
You are the one who is engaging in magical thinking ian. Cancellation and interference are real, measurable phenomenon that happen without the presence of matter and can not be explained by the view that EM fields are composed of particles and yet, you continue to hold the rigid belief that EM fields are particles even though phenomena are happening that can't be explained by your belief.