SSDD
Gold Member
- Nov 6, 2012
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emissivity -
- the ability of a surface to emit radiant energy compared to that of a black body at thesame temperature and with the same area.
Your definition doesn't appear to be written for gases.
CO2 has 3 main frequencies for emission/absorbance. 2, 3, and 15 microns, if memory stands. It is very close to a blackbody at those frequencies but only at those three. The other terrestrial IR frequencies have little or no reactivity. Even the 2, and 3 micron frequencies are mostly useless because the CO2 rarely gets hot enough to produce them, although it will always absorb them if present.
So the list is
1 micron 0
2 " 1
3 " 1
4 " 0
0
0
Etc
14 microns 0.5
15 microns 1
16 microns 0.5
17 microns 0
0
0
Etc.
How do you reasonably define the emissivity? By restricting the range of frequencies and temperatures.
If those frequencies increase the amount of radiative absorption and emission possible over simple air and oxygen, then the emissivity is increased..