Here are some excerpts from an, IMO, pretty good article that states the WTC collapse was NOT caused by fire alone. Nor was it caused by explosives. The cause is more complicated.
The WTC buildings were unique
"The towers were designed and built in the mid-1960s through the early 1970s. They represented a new approach to skyscrapers in that they were to be very lightweight and involved modular construction methods in order to accelerate the schedule and to reduce the costs."
The plane impact
"The early news reports noted how well the towers withstood the initial impact of the aircraft; however, when one recognizes that the buildings had more than 1,000 times the mass of the aircraft and had been designed to resist steady wind loads of 30 times the weight of the aircraft, this ability to withstand the initial impact is hardly surprising. Furthermore, since there was no significant wind on September 11, the outer perimeter columns were only stressed before the impact to around 1/3 of their 200 MPa design allowable."
"The only individual metal component of the aircraft that is comparable in strength to the box perimeter columns of the WTC is the keel beam at the bottom of the aircraft fuselage. While the aircraft impact undoubtedly destroyed several columns in the WTC perimeter wall, the number of columns lost on the initial impact was not large and the loads were shifted to remaining columns in this highly redundant structure. Of equal or even greater significance during this initial impact was the explosion when 90,000 L gallons of jet fuel, comprising nearly 1/3 of the aircraft’s weight, ignited.
The ensuing fire was clearly the principal cause of the collapse"
The fire
"The temperature of the fire was not uniform everywhere, and the temperature on the outside of the box columns was clearly lower than on the side facing the fire. The temperature along the 18 m long joists was certainly not uniform. Given the thermal expansion of steel, a 150°C temperature difference from one location to another will produce yield-level residual stresses. This produced distortions in the slender structural steel, which resulted in buckling failures. Thus, the failure of the steel was due to two factors: loss of strength due to the temperature of the fire, and loss of structural integrity due to distortion of the steel from the non-uniform temperatures in the fire."
The collapse
"Nearly every large building has a redundant design that allows for loss of one primary structural member, such as a column. However, when multiple members fail, the shifting loads eventually overstress the adjacent members and the collapse occurs like a row of dominoes falling down. "
"The perimeter tube design of the WTC was highly redundant. It survived the loss of several exterior columns due to aircraft impact, but the ensuing fire led to other steel failures. Many structural engineers believe that the weak points—the limiting factors on design allowables—were the angle clips that held the floor joists between the columns on the perimeter wall and the core structure (see
Figure 5). With a 700 Pa floor design allowable, each floor should have been able to support approximately 1,300 t beyond its own weight. The total weight of each tower was about 500,000 t."
"The World Trade Center was not defectively designed. No designer of the WTC anticipated, nor should have anticipated, a 90,000 L Molotov cocktail on one of the building floors. Skyscrapers are designed to support themselves for three hours in a fire even if the sprinkler system fails to operate. This time should be long enough to evacuate the occupants. The WTC towers lasted for one to two hours—less than the design life, but only because the fire fuel load was so large. No normal office fires would fill 4,000 square meters of floor space in the seconds in which the WTC fire developed. Usually, the fire would take up to an hour to spread so uniformly across the width and breadth of the building. This was a very large and rapidly progressing fire (very high heat but not unusually high temperature)."
Why Did the World Trade Center Collapse? Science, Engineering, and Speculation