You are not asking yourself the right questions.
You are the one not asking yourself the right questions ian...you should be asking yourself how goofy an individual has to be in order to believe that a substance which increases the emissivity of a thing could possibly be responsible for warming that thing...can you think of any real world example of such a thing happening or does it only happen in the case of magical CO2?
Good ole SSDD. He says things he thinks are smart but they usually come back to bite him in the ass.
This post of his is no exception. I told Westwall to consider the emissivity of the atmospheric window at zero, and the CO2 band at one.
What are the consequences? The atmosphere in the atmospheric window has none. It is as if it wasn't there at all. At those wavelengths the surface is radiating at full power into space, unimpeded. This is a case of the single object S-B equation being in play. All radiation loss, none coming back. You don't have to consider net power because the flow is only in one direction.
On the other hand, CO2 is absorbing ALL of the 15 micron radiation that the surface produces within metres of its emission. If the surface was warm enough to produce twice as much 15 micron radiation it would still be all totally absorbed.
This is where the two object S-B equation comes into play. Emissivity is very close to one for both objects, the area is equal because one object is enclosed by the other, only the temperature makes a difference between outgoing and incoming radiation at the surface.
Two things must be repeated for clarification. The ability to absorb a certain wavelength is exactly the same as the ability to emit the same wavelength, for any substance. It is called emissivity.
Area for a gas is a bit of a misnomer. The volume of gas that is capable of absorbing the radiation is a closer definition. Therefore the average temperature of the whole slab must be used in the S-B equation. Even this is not quite right but is close enough for our purposes. For 15 micron radiation the depth of the slab is roughly 10 metres, at STP.
Any object that absorbs and emits will affect a nearby object if it is replacing area exposed to a cooler environment, like space. If the nearby object has a power source then the equilibrium temperature will rise, if the nearby object is only warmer but not powered then the heat loss will be reduced.