You're over your head here ... clean air absorbs heat and increases temperatures on the surface ... the greenhouse effect ... c.f. US temperatures between Sept 11th and Sept 14th, 2001 ...
I don't know why you bring up smog, that's defined as a mix of smoke and fog ... and this increases Earth's albedo, the solar energy reflected back out into space does NOT contribute to surface temperatures ... isn't this your point in the OP, put MORE reflective material in the upper atmosphere to reflect sunlight away? ... the same thing can be done by increasing humidity and the corresponding increase in clouds ... and raising surface temperatures is a great way to do just that ... rough 7% increase in the mass of water vapor per degree Celsius ...
The Law commands equilibrium ... the CCC advocates are in felony violation of this Law ...