Si modo
Diamond Member
True, but that is after conversion to kinetic energy.CO2 re-emits? This is not fluorescence.But we're not saying that heat transfers from a colder to a warmer area. We're saying photons can move in any direction. You seem to be confusing the two. If as you say the moon doesn't emit IR, then it's because it was all absorbed. That's irrelevant to the subject in question, i.e. absorption and re-emission by CO2 or other gases.
CO2 absorbs a certain amount of IR radiation, a small portion of the mid IR spectrum. When that absorption happens, CO2 vibrates, internally, in a certain manner. THAT vibration is kinetic in nature. Kinetic energy causes some heat.
That heat is re-emitted radiation in proportion to T^4. When a beam of photons hits an opaque gas, it heats the gas, and the heated gas then re-emits the photons as blackbody radiation.
When a molecule emits a photon, that is fluorescence. This is a different mechanism - the bulk of the gas generates heat/IR from kinetic energy, no molecular emission involved.