You asked why we need to validate ice core sampling as a scientific method, and later stated that they are only used to show CO2 concentration, not to measure temperature.
1) One of the main points of the now infamous hockey stick graph shown in Al's movie was the direct relation between C02 concentrations and temperatures over the past 650,000 years. In fact, this link is a main "proof" of AGW theory. If you are willing to concede that ice core samples are not/can not be used to measure temperature, then we can assume Al's point on that relation is invalid right away.
2) If AGW theorists are going to continue to use ice core samples to show that CO2 levels have increased due to human intervention, then they need to be able to prove two things. A) The date of a sample with a reasonable tolerance for time (i.e. a sample advertised as being from a certain date would probably need to be from that actual date +/- ten years in order to show human intervention in climate change). B) The CO2 concentration in the atmosphere at the time of the sample.
Very few, if any, measurements go back in time as far as ice core samples. Therefore, without any VALIDATION, the time tolerance and CO2 accuracy of very old ice core samples is mere theory, not proof. What if the dating used in ice core samples is off by 10s, 100s, or 1000s of years? (dating inaccuracies have already shown to be off by 200 to over 1000 years). What if the CO2 levels in an air pocket of an ice core sample deteriorate over large spaces of time?
From my understanding, they have been validated by data actually taken at that time for about the past 40 years. A reasonable person might grant that the same levels of inaccuracy PROVEN over the past 40 years could be EXTRAPOLATED out to 100 years. To assume that those levels of inaccuracy hold steady for 650,000 years is theory.
Nothing else goes back 650,000 years to validate the level of accuracy of CO2 concentration found in the ice cores. We are making policy decisions that will impoverish millions of people. These decisions are only justified if the apocalyptic predictions based on a stand alone theory are true. How sure do you want to be?