Who am I to argue with the second law of thermodynamics?
But the photons from cooler to warmer doesn't violate the second law.
Photons don't move spontaneously from cool to warm....but if you feel like you can provide an example that violates the second law, by all means do show it...
Photons are emitted from anything that is warmer than absolute zero. We had this discussion before, talking about Stefan-Boltzman. Photons leave spontaneously. You seem to keep forgetting the term "NET". The warmer object emits higher energy photons than the cooler object, but they both emit. And the photons do not intercept each other, so some of the photons from the cooler object hit the warmer object. So the NET effect is a flow of energy from warmer to cooler, so the second law is not violated.
Nothing more than a mathematically constructed hypothesis based on assumptions.
This is the whole argument you guys have been fighting for weeks on. This drives me nuts!
The whole point of my thread was the physical conditions of matter that allow or disallow absorption of photons (EM radiation). CO2 is energy saturated in our atmosphere and once the molecule is in the positive or high state it can not receive more energy before it releases energy and returns to its low (neutral) dipole state.
MY whole point being, that our atmosphere is now totally transparent to LWIR and it can not cause further warming at current levels of CO2 saturation.