talanum1
Senior Member
- Jul 21, 2025
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The p-orbitals must be spherically symmetricly placed, so they must be located on the x, y and z axis in which case only 4 of them can orbit. So how is p_1/2 orbitals to display spin-orbit coupling? Only 4 of them can orbit because if the z axis also orbits (a twofold rotation) then L would not be z-directed aligned or anti-aligned to spin direction in the laboratory frame of reference.
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