Oceans have acidified more in the last 200 years than they did in the previous 21000

[skookerasbil]

So there are "Wider swing" in climate, but "ocean acidification" seem to move only in one direction...how does that happen exactly?

I see you're clueless and confused, as usual, frankie-boy. I'm afraid that, even if it were explained to you in detail, you are certainly far too retarded to comprehend that climate changes and ocean acidification are two entirely different physical phenomena linked only by the fact that increasing amounts of CO2 in the atmosphere are causing both of them.

meh...............

according to NASA..................

 

[CrusaderFrank]

So there are "Wider swing" in climate, but "ocean acidification" seem to move only in one direction...how does that happen exactly?

I see you're clueless and confused, as usual, frankie-boy. I'm afraid that, even if it were explained to you in detail, you are certainly far too retarded to comprehend that climate changes and ocean acidification are two entirely different physical phenomena linked only by the fact that increasing amounts of CO2 in the atmosphere are causing both of them.

But you can't ever show us how this works in a lab, amiright?

 

[CrusaderFrank]

So there are "Wider swing" in climate, but "ocean acidification" seem to move only in one direction...how does that happen exactly?

I see you're clueless and confused, as usual, frankie-boy. I'm afraid that, even if it were explained to you in detail, you are certainly far too retarded to comprehend that climate changes and ocean acidification are two entirely different physical phenomena linked only by the fact that increasing amounts of CO2 in the atmosphere are causing both of them.

Bigger squirrels too, right?

 

[RollingThunder]

So there are "Wider swing" in climate, but "ocean acidification" seem to move only in one direction...how does that happen exactly?

I see you're clueless and confused, as usual, frankie-boy. I'm afraid that, even if it were explained to you in detail, you are certainly far too retarded to comprehend that climate changes and ocean acidification are two entirely different physical phenomena linked only by the fact that increasing amounts of CO2 in the atmosphere are causing both of them.

But you can't ever show us how this works in a lab, amiright?

No, of course not. You're never right. You're a completely clueless retard.

You've been shown the lab experiments supporting the Greenhouse Effect many times but you have your head jammed too far up your pansy ass to see it and you're too stupid to understand it anyway.

Anti-science reality deniers like you, frankie-boy, are always so confused and clueless.

I can't be bothered to copy all of the links and insert them so you'll just have to go to the original site to check the links.

Papers on laboratory measurements of CO2 absorption properties

September 25, 2009
(free to reproduce)

This is a list of papers on laboratory measurements of the absorption properties of carbon dioxide. In the context of these paperlists this is a difficult subject because only few of the papers are freely available online, so we have to settle on abstracts only (of course, interested reader can purchase the full texts for the papers from the linked abstract pages). However, I don’t think that matters that much because the main point of this list really is to show that the basic research on the subject exists. The list is not complete, and will most likely be updated in the future in order to make it more thorough and more representative.

UPDATE (February 6, 2010): Miller & Watts (1984) added.
UPDATE (July 25, 2010): I modified the introduction paragraph a little to reflect the current content of the list. The old text was a little outdated.
UPDATE (June 22, 2010): Lecher & Pernter (1881) added.
UPDATE (March 31, 2010): Tubbs & Williams (1972), Rubens & Aschkinass (1898) and Ångström (1900) added.
UPDATE (March 6, 2010): Barker (1922) added.
UPDATE (November 19, 2009): Predoi-Cross et al. (2007) added.
UPDATE (September 25, 2009): Miller & Brown (2004) added, thanks to John Cook for bringing it to my attention (see the discussion section below).

Spectroscopic database of CO2 line parameters: 4300–7000 cm−1 – Toth et al. (2008) “A new spectroscopic database for carbon dioxide in the near infrared is presented to support remote sensing of the terrestrial planets (Mars, Venus and the Earth). The compilation contains over 28,500 transitions of 210 bands from 4300 to 7000 cm−1…”

Line shape parameters measurement and computations for self-broadened carbon dioxide transitions in the 30012 ← 00001 and 30013 ← 00001 bands, line mixing, and speed dependence – Predoi-Cross et al. (2007) “Transitions of pure carbon dioxide have been measured using a Fourier transform spectrometer in the 30012 ← 00001 and 30013 ← 00001 vibrational bands. The room temperature spectra, recorded at a resolution of 0.008 cm−1, were analyzed using the Voigt model and a Speed Dependent Voigt line shape model that includes a pressure dependent narrowing parameter. Intensities, self-induced pressure broadening, shifts, and weak line mixing coefficients are determined. The results obtained are consistent with other studies in addition to the theoretically calculated values.” [Full text]

Spectroscopic challenges for high accuracy retrievals of atmospheric CO2 and the Orbiting Carbon Observatory (OCO) experiment – Miller et al. (2005) “The space-based Orbiting Carbon Observatory (OCO) mission will achieve global measurements needed to distinguish spatial and temporal gradients in the CO2 column. Scheduled by NASA to launch in 2008, the instrument will obtain averaged dry air mole fraction (XCO2) with a precision of 1 part per million (0.3%) in order to quantify the variation of CO2 sources and sinks and to improve future climate forecasts. Retrievals of XCO2 from ground-based measurements require even higher precisions to validate the satellite data and link them accurately and without bias to the World Meteorological Organization (WMO) standard for atmospheric CO2 observations. These retrievals will require CO2 spectroscopic parameters with unprecedented accuracy. Here we present the experimental and data analysis methods implemented in laboratory studies in order to achieve this challenging goal.”

Near infrared spectroscopy of carbon dioxide I. 16O12C16O line positions – Miller & Brown (2004) “High-resolution near-infrared (4000–9000 cm-1) spectra of carbon dioxide have been recorded using the McMath–Pierce Fourier transform spectrometer at the Kitt Peak National Solar Observatory. Some 2500 observed positions have been used to determine spectroscopic constants for 53 different vibrational states of the 16O12C16O isotopologue, including eight vibrational states for which laboratory spectra have not previously been reported. … This work reduces CO2 near-infrared line position uncertainties by a factor of 10 or more compared to the 2000 HITRAN line list, which has not been modified since the comprehensive work of Rothman et al. [J. Quant. Spectrosc. Rad. Transfer 48 (1992) 537].” [Full text]

Spectra calculations in central and wing regions of CO2 IR bands between 10 and 20 μm. I: model and laboratory measurements – Niro et al. (2004) “Temperature (200–300 K) and pressure (70–200 atm) dependent laboratory measurements of infrared transmission by CO2–N2 mixtures have been made. From these experiments the absorption coefficient is reconstructed, over a range of several orders of magnitude, between 600 and 1000 cm−1.”

Collisional effects on spectral line-shapes – Boulet (2004) “The growing concern of mankind for the understanding and preserving of its environment has stimulated great interest for the study of planetary atmospheres and, first of all, for that of the Earth. Onboard spectrometers now provide more and more precise information on the transmission and emission of radiation by these atmospheres. Its treatment by ‘retrieval’ technics, in order to extract vertical profiles (pressure, temperature, volume mixing ratios) requires precise modeling of infrared absorption spectra. Within this framework, accounting for the influence of pressure on the absorption shape is crucial. These effects of inter-molecular collisions between the optically active species and the ‘perturbers’ are complex and of various types depending mostly on the density of perturbers. The present paper attempts to review and illustrate, through a few examples, the state of the art in this field.”

On far-wing Raman profiles by CO2 – Benech et al. (2002) “Despite the excellent agreement observed in N2 here, a substantial inconsistency between theory and experiment was found in the wing of the spectrum. Although the influence of other missing processes or neighboring bands cannot be totally excluded, our findings rather suggest that highly anisotropic perturbers, such as CO2, are improperly described when they are handled as point-like molecules, a cornerstone hypothesis in the approach employed.”

Collision-induced scattering in CO2 gas – Teboul et al. (1995) “Carbon-dioxide gas rototranslational scattering has been measured at 294.5 K in the frequency range 10–1000 cm−1 at 23 amagat. The depolarization ratio of scattered intensities in the frequency range 10–1000 cm−1 is recorded. The theoretical and experimental spectra in the frequency range 10–470 cm−1 are compared.”

The HITRAN database: 1986 edition – Rothman et al. (1987) “A description and summary of the latest edition of the AFGL HITRAN molecular absorption parameters database are presented. This new database combines the information for the seven principal atmospheric absorbers and twenty-one additional molecular species previously contained on the AFGL atmospheric absorption line parameter compilation and on the trace gas compilation.”

Rotational structure in the infrared spectra of carbon dioxide and nitrous oxide dimers – Miller & Watts (1984) “High-resolution infrared predissociation spectra have been measured for dilute mixtures of CO2 and N2O in helium. Rotational fine structure is clearly resolved for both (CO2)2 and (N2O)2, the linewidths being instrument-limited. This establishes that predissociation lifetimes are longer than approximately 50 ns.”

Broadening of Infrared Absorption Lines at Reduced Temperatures: Carbon Dioxide – Tubbs & Williams (1972) “An evacuated high-resolution Czerny-Turner spectrograph, which is described in this paper, has been used to determine the strengths S and self-broadening parameters γ0 for lines in the R branch of the ν3 fundamental of 12C16O2 at 298 and at 207 K. The values of γ0 at 207 K are greater than those to be expected on the basis of a fixed collision cross section σ.”

Investigation of the Absorption of Infrared Radiation by Atmospheric Gases – Burch et al. (1970) “From spectral transmittance curves of very large samples of CO2 we have determined coefficients for intrinsic absorption and pressure-induced absorption from approximately 1130/cm to 1835/cm.”

Absorption of Infrared Radiant Energy by CO2 and H2O. IV. Shapes of Collision-Broadened CO2 Lines – Burch et al. (1969) “The shapes of the extreme wings of self-broadened CO2 lines have been investigated in three spectral regions near 7000, 3800, and 2400 cm−1. … New information has been obtained about the shapes of self-broadened CO2 lines as well as CO2 lines broadened by N2, O2, Ar, He, and H2.”

High-Temperature Spectral Emissivities and Total Intensities of the 15-µ Band System of CO2 – Ludwig et al. (1966) “Spectral-emissivity measurements of the 15-µ band of CO2 were made in the temperature range from 1000° to 2300°K.”

Line shape in the wing beyond the band head of the 4·3 μ band of CO2 – Winters et al. (1964) “Quantitative absorpance measurements have been made in pure CO2 and mixtures of CO2 with N2 and O2 in a 10 m White Perkin-Elmer cell. With absorbing paths up to 50 m-atm, results have been obtained from the band head at 2397 cm−1 to 2575 cm−1.”

Emissivity of Carbon Dioxide at 4.3 µ – Davies (1964) “The emissivity of carbon dioxide has been measured for temperatures from 1500° to 3000°K over the wavelength range from 4.40 to 5.30 µ.”

Absorption Line Broadening in the Infrared – Burch et al. (1962) “The effects of various gases on the absorption bands of nitrous oxide, carbon monoxide, methane, carbon dioxide, and water vapor have been investigated.”

Total Absorptance of Carbon Dioxide in the Infrared – Burch et al. (1962) “Total absorptance… has been determined as a function of absorber concentration w and equivalent pressure Pe for the major infrared absorption bands of carbon dioxide with centers at 3716, 3609, 2350, 1064, and 961 cm−1.”

Rotation-Vibration Spectra of Diatomic and Simple Polyatomic Molecules with Long Absorbing Paths – Herzberg & Herzberg (1953) “The spectrum of CO2 in the photographic infrared has been studied with absorbing paths up to 5500 m. Thirteen absorption bands were found of which eleven have been analyzed in detail.”

The Infrared Absorption Spectrum of Carbon Dioxide – Martin & Barker (1932) “The complete infrared spectrum of CO2 may consistently be explained in terms of a linear symmetrical model, making use of the selection rules developed by Dennison and the resonance interaction introduced by Fermi. The inactive fundamental ν1 appears only in combination bands, but ν2 at 15μ and ν3 at 4.3μ absorb intensely.”

Carbon Dioxide Absorption in the Near Infra-Red – Barker (1922) “Infra-red absorption bands of CO2 at 2.7 and 4.3 μ. – New absorption curves have been obtained, using a special prism-grating double spectrometer of higher resolution (Figs. 1-3). The 2.7 μ region, heretofore considered to be a doublet, proves to be a pair of doublets, with centers at approximately 2.694 μ and 2.767 μ. The 4.3 μ band appears as a single doublet with center at 4.253 μ. The frequency difference between maxima is nearly the same for each of the three doublets, and equal to 4.5 x 1011. Complete resolution of the band series was not effected, even though the slit included only 12 A for the 2.7 μ region, but there is evidently a complicated structure, with a “head” in each case on the side of shorter wave-lengths. The existence of this head for the 4.3 μ band is also indicated by a comparison with the emission spectrum from a bunsen flame, and the difference in wave-length of the maxima of emission and absorption is explained as a temperature effect similar to that observed with other doublets.” [For free full text, click PDF or GIF links in the linked abstract page]

Ueber die Bedeutung des Wasserdampfes und der Kohlensäure bei der Absorption der Erdatmosphäre – Ångström (1900)

Observations on the Absorption and Emission of Aqueous Vapor and Carbon Dioxide in the Infra-Red Spectrum – Rubens & Aschkinass (1898) “Our experiments carried out as described above on the absorption spectrum carbon dioxide very soon showed that we were dealing with a single absorption band whose maximum lies near λ = 14.7 μ. … The whole region of absorption is limited to the interval from 12.5 μ to 16 μ, with the maximum at 14.7 μ.” [For free full text, click PDF or GIF links in the linked abstract page]

On the absorption of dark heat-rays by gases and vapours – Lecher & Pernter (1881) Svante Arrhenius wrote in his famous 1897 paper: “Tyndall held the opinion that the water-vapour has the greatest influence, whilst other authors, for instance Lecher and Pernter, are inclined to think that the carbonic acid plays the more important part.”.

The Bakerian Lecture – On the Absorption and Radiation of Heat by Gases and Vapours, and on the Physical Connexion of Radiation, Absorption, and Conduction – Tyndall (1861) 150 years ago John Tyndall already showed that carbon dioxide absorbs infrared radiation. [Full text] [Wikipedia: John Tyndall]

Closely related

The HITRAN Database – The laboratory work results on the absorption properties of carbon dioxide (and many other molecules) is contained in this database.

(In accordance with Title 17 U.S.C. Section 107, this material is distributed without profit to those who have expressed a prior interest in receiving the included information for research and educational purposes.)

 

[CrusaderFrank]

I see you're clueless and confused, as usual, frankie-boy. I'm afraid that, even if it were explained to you in detail, you are certainly far too retarded to comprehend that climate changes and ocean acidification are two entirely different physical phenomena linked only by the fact that increasing amounts of CO2 in the atmosphere are causing both of them.

But you can't ever show us how this works in a lab, amiright?

No, of course not. You're never right. You're a completely clueless retard.

You've been shown the lab experiments supporting the Greenhouse Effect many times but you have your head jammed too far up your pansy ass to see it and you're too stupid to understand it anyway.

Anti-science reality deniers like you, frankie-boy, are always so confused and clueless.

I can't be bothered to copy all of the links and insert them so you'll just have to go to the original site to check the links.

Papers on laboratory measurements of CO2 absorption properties

September 25, 2009
(free to reproduce)

This is a list of papers on laboratory measurements of the absorption properties of carbon dioxide. In the context of these paperlists this is a difficult subject because only few of the papers are freely available online, so we have to settle on abstracts only (of course, interested reader can purchase the full texts for the papers from the linked abstract pages). However, I don’t think that matters that much because the main point of this list really is to show that the basic research on the subject exists. The list is not complete, and will most likely be updated in the future in order to make it more thorough and more representative.

UPDATE (February 6, 2010): Miller & Watts (1984) added.
UPDATE (July 25, 2010): I modified the introduction paragraph a little to reflect the current content of the list. The old text was a little outdated.
UPDATE (June 22, 2010): Lecher & Pernter (1881) added.
UPDATE (March 31, 2010): Tubbs & Williams (1972), Rubens & Aschkinass (1898) and Ångström (1900) added.
UPDATE (March 6, 2010): Barker (1922) added.
UPDATE (November 19, 2009): Predoi-Cross et al. (2007) added.
UPDATE (September 25, 2009): Miller & Brown (2004) added, thanks to John Cook for bringing it to my attention (see the discussion section below).

Spectroscopic database of CO2 line parameters: 4300–7000 cm−1 – Toth et al. (2008) “A new spectroscopic database for carbon dioxide in the near infrared is presented to support remote sensing of the terrestrial planets (Mars, Venus and the Earth). The compilation contains over 28,500 transitions of 210 bands from 4300 to 7000 cm−1…”

Line shape parameters measurement and computations for self-broadened carbon dioxide transitions in the 30012 ← 00001 and 30013 ← 00001 bands, line mixing, and speed dependence – Predoi-Cross et al. (2007) “Transitions of pure carbon dioxide have been measured using a Fourier transform spectrometer in the 30012 ← 00001 and 30013 ← 00001 vibrational bands. The room temperature spectra, recorded at a resolution of 0.008 cm−1, were analyzed using the Voigt model and a Speed Dependent Voigt line shape model that includes a pressure dependent narrowing parameter. Intensities, self-induced pressure broadening, shifts, and weak line mixing coefficients are determined. The results obtained are consistent with other studies in addition to the theoretically calculated values.” [Full text]

Spectroscopic challenges for high accuracy retrievals of atmospheric CO2 and the Orbiting Carbon Observatory (OCO) experiment – Miller et al. (2005) “The space-based Orbiting Carbon Observatory (OCO) mission will achieve global measurements needed to distinguish spatial and temporal gradients in the CO2 column. Scheduled by NASA to launch in 2008, the instrument will obtain averaged dry air mole fraction (XCO2) with a precision of 1 part per million (0.3%) in order to quantify the variation of CO2 sources and sinks and to improve future climate forecasts. Retrievals of XCO2 from ground-based measurements require even higher precisions to validate the satellite data and link them accurately and without bias to the World Meteorological Organization (WMO) standard for atmospheric CO2 observations. These retrievals will require CO2 spectroscopic parameters with unprecedented accuracy. Here we present the experimental and data analysis methods implemented in laboratory studies in order to achieve this challenging goal.”

Near infrared spectroscopy of carbon dioxide I. 16O12C16O line positions – Miller & Brown (2004) “High-resolution near-infrared (4000–9000 cm-1) spectra of carbon dioxide have been recorded using the McMath–Pierce Fourier transform spectrometer at the Kitt Peak National Solar Observatory. Some 2500 observed positions have been used to determine spectroscopic constants for 53 different vibrational states of the 16O12C16O isotopologue, including eight vibrational states for which laboratory spectra have not previously been reported. … This work reduces CO2 near-infrared line position uncertainties by a factor of 10 or more compared to the 2000 HITRAN line list, which has not been modified since the comprehensive work of Rothman et al. [J. Quant. Spectrosc. Rad. Transfer 48 (1992) 537].” [Full text]

Spectra calculations in central and wing regions of CO2 IR bands between 10 and 20 μm. I: model and laboratory measurements – Niro et al. (2004) “Temperature (200–300 K) and pressure (70–200 atm) dependent laboratory measurements of infrared transmission by CO2–N2 mixtures have been made. From these experiments the absorption coefficient is reconstructed, over a range of several orders of magnitude, between 600 and 1000 cm−1.”

Collisional effects on spectral line-shapes – Boulet (2004) “The growing concern of mankind for the understanding and preserving of its environment has stimulated great interest for the study of planetary atmospheres and, first of all, for that of the Earth. Onboard spectrometers now provide more and more precise information on the transmission and emission of radiation by these atmospheres. Its treatment by ‘retrieval’ technics, in order to extract vertical profiles (pressure, temperature, volume mixing ratios) requires precise modeling of infrared absorption spectra. Within this framework, accounting for the influence of pressure on the absorption shape is crucial. These effects of inter-molecular collisions between the optically active species and the ‘perturbers’ are complex and of various types depending mostly on the density of perturbers. The present paper attempts to review and illustrate, through a few examples, the state of the art in this field.”

On far-wing Raman profiles by CO2 – Benech et al. (2002) “Despite the excellent agreement observed in N2 here, a substantial inconsistency between theory and experiment was found in the wing of the spectrum. Although the influence of other missing processes or neighboring bands cannot be totally excluded, our findings rather suggest that highly anisotropic perturbers, such as CO2, are improperly described when they are handled as point-like molecules, a cornerstone hypothesis in the approach employed.”

Collision-induced scattering in CO2 gas – Teboul et al. (1995) “Carbon-dioxide gas rototranslational scattering has been measured at 294.5 K in the frequency range 10–1000 cm−1 at 23 amagat. The depolarization ratio of scattered intensities in the frequency range 10–1000 cm−1 is recorded. The theoretical and experimental spectra in the frequency range 10–470 cm−1 are compared.”

The HITRAN database: 1986 edition – Rothman et al. (1987) “A description and summary of the latest edition of the AFGL HITRAN molecular absorption parameters database are presented. This new database combines the information for the seven principal atmospheric absorbers and twenty-one additional molecular species previously contained on the AFGL atmospheric absorption line parameter compilation and on the trace gas compilation.”

Rotational structure in the infrared spectra of carbon dioxide and nitrous oxide dimers – Miller & Watts (1984) “High-resolution infrared predissociation spectra have been measured for dilute mixtures of CO2 and N2O in helium. Rotational fine structure is clearly resolved for both (CO2)2 and (N2O)2, the linewidths being instrument-limited. This establishes that predissociation lifetimes are longer than approximately 50 ns.”

Broadening of Infrared Absorption Lines at Reduced Temperatures: Carbon Dioxide – Tubbs & Williams (1972) “An evacuated high-resolution Czerny-Turner spectrograph, which is described in this paper, has been used to determine the strengths S and self-broadening parameters γ0 for lines in the R branch of the ν3 fundamental of 12C16O2 at 298 and at 207 K. The values of γ0 at 207 K are greater than those to be expected on the basis of a fixed collision cross section σ.”

Investigation of the Absorption of Infrared Radiation by Atmospheric Gases – Burch et al. (1970) “From spectral transmittance curves of very large samples of CO2 we have determined coefficients for intrinsic absorption and pressure-induced absorption from approximately 1130/cm to 1835/cm.”

Absorption of Infrared Radiant Energy by CO2 and H2O. IV. Shapes of Collision-Broadened CO2 Lines – Burch et al. (1969) “The shapes of the extreme wings of self-broadened CO2 lines have been investigated in three spectral regions near 7000, 3800, and 2400 cm−1. … New information has been obtained about the shapes of self-broadened CO2 lines as well as CO2 lines broadened by N2, O2, Ar, He, and H2.”

High-Temperature Spectral Emissivities and Total Intensities of the 15-µ Band System of CO2 – Ludwig et al. (1966) “Spectral-emissivity measurements of the 15-µ band of CO2 were made in the temperature range from 1000° to 2300°K.”

Line shape in the wing beyond the band head of the 4·3 μ band of CO2 – Winters et al. (1964) “Quantitative absorpance measurements have been made in pure CO2 and mixtures of CO2 with N2 and O2 in a 10 m White Perkin-Elmer cell. With absorbing paths up to 50 m-atm, results have been obtained from the band head at 2397 cm−1 to 2575 cm−1.”

Emissivity of Carbon Dioxide at 4.3 µ – Davies (1964) “The emissivity of carbon dioxide has been measured for temperatures from 1500° to 3000°K over the wavelength range from 4.40 to 5.30 µ.”

Absorption Line Broadening in the Infrared – Burch et al. (1962) “The effects of various gases on the absorption bands of nitrous oxide, carbon monoxide, methane, carbon dioxide, and water vapor have been investigated.”

Total Absorptance of Carbon Dioxide in the Infrared – Burch et al. (1962) “Total absorptance… has been determined as a function of absorber concentration w and equivalent pressure Pe for the major infrared absorption bands of carbon dioxide with centers at 3716, 3609, 2350, 1064, and 961 cm−1.”

Rotation-Vibration Spectra of Diatomic and Simple Polyatomic Molecules with Long Absorbing Paths – Herzberg & Herzberg (1953) “The spectrum of CO2 in the photographic infrared has been studied with absorbing paths up to 5500 m. Thirteen absorption bands were found of which eleven have been analyzed in detail.”

The Infrared Absorption Spectrum of Carbon Dioxide – Martin & Barker (1932) “The complete infrared spectrum of CO2 may consistently be explained in terms of a linear symmetrical model, making use of the selection rules developed by Dennison and the resonance interaction introduced by Fermi. The inactive fundamental ν1 appears only in combination bands, but ν2 at 15μ and ν3 at 4.3μ absorb intensely.”

Carbon Dioxide Absorption in the Near Infra-Red – Barker (1922) “Infra-red absorption bands of CO2 at 2.7 and 4.3 μ. – New absorption curves have been obtained, using a special prism-grating double spectrometer of higher resolution (Figs. 1-3). The 2.7 μ region, heretofore considered to be a doublet, proves to be a pair of doublets, with centers at approximately 2.694 μ and 2.767 μ. The 4.3 μ band appears as a single doublet with center at 4.253 μ. The frequency difference between maxima is nearly the same for each of the three doublets, and equal to 4.5 x 1011. Complete resolution of the band series was not effected, even though the slit included only 12 A for the 2.7 μ region, but there is evidently a complicated structure, with a “head” in each case on the side of shorter wave-lengths. The existence of this head for the 4.3 μ band is also indicated by a comparison with the emission spectrum from a bunsen flame, and the difference in wave-length of the maxima of emission and absorption is explained as a temperature effect similar to that observed with other doublets.” [For free full text, click PDF or GIF links in the linked abstract page]

Ueber die Bedeutung des Wasserdampfes und der Kohlensäure bei der Absorption der Erdatmosphäre – Ångström (1900)

Observations on the Absorption and Emission of Aqueous Vapor and Carbon Dioxide in the Infra-Red Spectrum – Rubens & Aschkinass (1898) “Our experiments carried out as described above on the absorption spectrum carbon dioxide very soon showed that we were dealing with a single absorption band whose maximum lies near λ = 14.7 μ. … The whole region of absorption is limited to the interval from 12.5 μ to 16 μ, with the maximum at 14.7 μ.” [For free full text, click PDF or GIF links in the linked abstract page]

On the absorption of dark heat-rays by gases and vapours – Lecher & Pernter (1881) Svante Arrhenius wrote in his famous 1897 paper: “Tyndall held the opinion that the water-vapour has the greatest influence, whilst other authors, for instance Lecher and Pernter, are inclined to think that the carbonic acid plays the more important part.”.

The Bakerian Lecture – On the Absorption and Radiation of Heat by Gases and Vapours, and on the Physical Connexion of Radiation, Absorption, and Conduction – Tyndall (1861) 150 years ago John Tyndall already showed that carbon dioxide absorbs infrared radiation. [Full text] [Wikipedia: John Tyndall]

Closely related

The HITRAN Database – The laboratory work results on the absorption properties of carbon dioxide (and many other molecules) is contained in this database.

(In accordance with Title 17 U.S.C. Section 107, this material is distributed without profit to those who have expressed a prior interest in receiving the included information for research and educational purposes.)

yes, the same tired old articles that don't show how AGW caused swings in temperature and turns the oceans to gastric juice

[ame=http://www.youtube.com/watch?v=Hzsou4RSb3k]Frank Zappa - Outside Now (live in Paris, 1980) - YouTube[/ame]

Has nothing to do with Oceans acidification either but its more fun to listen to than your stupid links

 

[skookerasbil]

I see you're clueless and confused, as usual, frankie-boy. I'm afraid that, even if it were explained to you in detail, you are certainly far too retarded to comprehend that climate changes and ocean acidification are two entirely different physical phenomena linked only by the fact that increasing amounts of CO2 in the atmosphere are causing both of them.

But you can't ever show us how this works in a lab, amiright?

No, of course not. You're never right. You're a completely clueless retard.

You've been shown the lab experiments supporting the Greenhouse Effect many times but you have your head jammed too far up your pansy ass to see it and you're too stupid to understand it anyway.

Anti-science reality deniers like you, frankie-boy, are always so confused and clueless.

I can't be bothered to copy all of the links and insert them so you'll just have to go to the original site to check the links.

Papers on laboratory measurements of CO2 absorption properties

September 25, 2009
(free to reproduce)

This is a list of papers on laboratory measurements of the absorption properties of carbon dioxide. In the context of these paperlists this is a difficult subject because only few of the papers are freely available online, so we have to settle on abstracts only (of course, interested reader can purchase the full texts for the papers from the linked abstract pages). However, I don’t think that matters that much because the main point of this list really is to show that the basic research on the subject exists. The list is not complete, and will most likely be updated in the future in order to make it more thorough and more representative.

UPDATE (February 6, 2010): Miller & Watts (1984) added.
UPDATE (July 25, 2010): I modified the introduction paragraph a little to reflect the current content of the list. The old text was a little outdated.
UPDATE (June 22, 2010): Lecher & Pernter (1881) added.
UPDATE (March 31, 2010): Tubbs & Williams (1972), Rubens & Aschkinass (1898) and Ångström (1900) added.
UPDATE (March 6, 2010): Barker (1922) added.
UPDATE (November 19, 2009): Predoi-Cross et al. (2007) added.
UPDATE (September 25, 2009): Miller & Brown (2004) added, thanks to John Cook for bringing it to my attention (see the discussion section below).

Spectroscopic database of CO2 line parameters: 4300–7000 cm−1 – Toth et al. (2008) “A new spectroscopic database for carbon dioxide in the near infrared is presented to support remote sensing of the terrestrial planets (Mars, Venus and the Earth). The compilation contains over 28,500 transitions of 210 bands from 4300 to 7000 cm−1…”

Line shape parameters measurement and computations for self-broadened carbon dioxide transitions in the 30012 ← 00001 and 30013 ← 00001 bands, line mixing, and speed dependence – Predoi-Cross et al. (2007) “Transitions of pure carbon dioxide have been measured using a Fourier transform spectrometer in the 30012 ← 00001 and 30013 ← 00001 vibrational bands. The room temperature spectra, recorded at a resolution of 0.008 cm−1, were analyzed using the Voigt model and a Speed Dependent Voigt line shape model that includes a pressure dependent narrowing parameter. Intensities, self-induced pressure broadening, shifts, and weak line mixing coefficients are determined. The results obtained are consistent with other studies in addition to the theoretically calculated values.” [Full text]

Spectroscopic challenges for high accuracy retrievals of atmospheric CO2 and the Orbiting Carbon Observatory (OCO) experiment – Miller et al. (2005) “The space-based Orbiting Carbon Observatory (OCO) mission will achieve global measurements needed to distinguish spatial and temporal gradients in the CO2 column. Scheduled by NASA to launch in 2008, the instrument will obtain averaged dry air mole fraction (XCO2) with a precision of 1 part per million (0.3%) in order to quantify the variation of CO2 sources and sinks and to improve future climate forecasts. Retrievals of XCO2 from ground-based measurements require even higher precisions to validate the satellite data and link them accurately and without bias to the World Meteorological Organization (WMO) standard for atmospheric CO2 observations. These retrievals will require CO2 spectroscopic parameters with unprecedented accuracy. Here we present the experimental and data analysis methods implemented in laboratory studies in order to achieve this challenging goal.”

Near infrared spectroscopy of carbon dioxide I. 16O12C16O line positions – Miller & Brown (2004) “High-resolution near-infrared (4000–9000 cm-1) spectra of carbon dioxide have been recorded using the McMath–Pierce Fourier transform spectrometer at the Kitt Peak National Solar Observatory. Some 2500 observed positions have been used to determine spectroscopic constants for 53 different vibrational states of the 16O12C16O isotopologue, including eight vibrational states for which laboratory spectra have not previously been reported. … This work reduces CO2 near-infrared line position uncertainties by a factor of 10 or more compared to the 2000 HITRAN line list, which has not been modified since the comprehensive work of Rothman et al. [J. Quant. Spectrosc. Rad. Transfer 48 (1992) 537].” [Full text]

Spectra calculations in central and wing regions of CO2 IR bands between 10 and 20 μm. I: model and laboratory measurements – Niro et al. (2004) “Temperature (200–300 K) and pressure (70–200 atm) dependent laboratory measurements of infrared transmission by CO2–N2 mixtures have been made. From these experiments the absorption coefficient is reconstructed, over a range of several orders of magnitude, between 600 and 1000 cm−1.”

Collisional effects on spectral line-shapes – Boulet (2004) “The growing concern of mankind for the understanding and preserving of its environment has stimulated great interest for the study of planetary atmospheres and, first of all, for that of the Earth. Onboard spectrometers now provide more and more precise information on the transmission and emission of radiation by these atmospheres. Its treatment by ‘retrieval’ technics, in order to extract vertical profiles (pressure, temperature, volume mixing ratios) requires precise modeling of infrared absorption spectra. Within this framework, accounting for the influence of pressure on the absorption shape is crucial. These effects of inter-molecular collisions between the optically active species and the ‘perturbers’ are complex and of various types depending mostly on the density of perturbers. The present paper attempts to review and illustrate, through a few examples, the state of the art in this field.”

On far-wing Raman profiles by CO2 – Benech et al. (2002) “Despite the excellent agreement observed in N2 here, a substantial inconsistency between theory and experiment was found in the wing of the spectrum. Although the influence of other missing processes or neighboring bands cannot be totally excluded, our findings rather suggest that highly anisotropic perturbers, such as CO2, are improperly described when they are handled as point-like molecules, a cornerstone hypothesis in the approach employed.”

Collision-induced scattering in CO2 gas – Teboul et al. (1995) “Carbon-dioxide gas rototranslational scattering has been measured at 294.5 K in the frequency range 10–1000 cm−1 at 23 amagat. The depolarization ratio of scattered intensities in the frequency range 10–1000 cm−1 is recorded. The theoretical and experimental spectra in the frequency range 10–470 cm−1 are compared.”

The HITRAN database: 1986 edition – Rothman et al. (1987) “A description and summary of the latest edition of the AFGL HITRAN molecular absorption parameters database are presented. This new database combines the information for the seven principal atmospheric absorbers and twenty-one additional molecular species previously contained on the AFGL atmospheric absorption line parameter compilation and on the trace gas compilation.”

Rotational structure in the infrared spectra of carbon dioxide and nitrous oxide dimers – Miller & Watts (1984) “High-resolution infrared predissociation spectra have been measured for dilute mixtures of CO2 and N2O in helium. Rotational fine structure is clearly resolved for both (CO2)2 and (N2O)2, the linewidths being instrument-limited. This establishes that predissociation lifetimes are longer than approximately 50 ns.”

Broadening of Infrared Absorption Lines at Reduced Temperatures: Carbon Dioxide – Tubbs & Williams (1972) “An evacuated high-resolution Czerny-Turner spectrograph, which is described in this paper, has been used to determine the strengths S and self-broadening parameters γ0 for lines in the R branch of the ν3 fundamental of 12C16O2 at 298 and at 207 K. The values of γ0 at 207 K are greater than those to be expected on the basis of a fixed collision cross section σ.”

Investigation of the Absorption of Infrared Radiation by Atmospheric Gases – Burch et al. (1970) “From spectral transmittance curves of very large samples of CO2 we have determined coefficients for intrinsic absorption and pressure-induced absorption from approximately 1130/cm to 1835/cm.”

Absorption of Infrared Radiant Energy by CO2 and H2O. IV. Shapes of Collision-Broadened CO2 Lines – Burch et al. (1969) “The shapes of the extreme wings of self-broadened CO2 lines have been investigated in three spectral regions near 7000, 3800, and 2400 cm−1. … New information has been obtained about the shapes of self-broadened CO2 lines as well as CO2 lines broadened by N2, O2, Ar, He, and H2.”

High-Temperature Spectral Emissivities and Total Intensities of the 15-µ Band System of CO2 – Ludwig et al. (1966) “Spectral-emissivity measurements of the 15-µ band of CO2 were made in the temperature range from 1000° to 2300°K.”

Line shape in the wing beyond the band head of the 4·3 μ band of CO2 – Winters et al. (1964) “Quantitative absorpance measurements have been made in pure CO2 and mixtures of CO2 with N2 and O2 in a 10 m White Perkin-Elmer cell. With absorbing paths up to 50 m-atm, results have been obtained from the band head at 2397 cm−1 to 2575 cm−1.”

Emissivity of Carbon Dioxide at 4.3 µ – Davies (1964) “The emissivity of carbon dioxide has been measured for temperatures from 1500° to 3000°K over the wavelength range from 4.40 to 5.30 µ.”

Absorption Line Broadening in the Infrared – Burch et al. (1962) “The effects of various gases on the absorption bands of nitrous oxide, carbon monoxide, methane, carbon dioxide, and water vapor have been investigated.”

Total Absorptance of Carbon Dioxide in the Infrared – Burch et al. (1962) “Total absorptance… has been determined as a function of absorber concentration w and equivalent pressure Pe for the major infrared absorption bands of carbon dioxide with centers at 3716, 3609, 2350, 1064, and 961 cm−1.”

Rotation-Vibration Spectra of Diatomic and Simple Polyatomic Molecules with Long Absorbing Paths – Herzberg & Herzberg (1953) “The spectrum of CO2 in the photographic infrared has been studied with absorbing paths up to 5500 m. Thirteen absorption bands were found of which eleven have been analyzed in detail.”

The Infrared Absorption Spectrum of Carbon Dioxide – Martin & Barker (1932) “The complete infrared spectrum of CO2 may consistently be explained in terms of a linear symmetrical model, making use of the selection rules developed by Dennison and the resonance interaction introduced by Fermi. The inactive fundamental ν1 appears only in combination bands, but ν2 at 15μ and ν3 at 4.3μ absorb intensely.”

Carbon Dioxide Absorption in the Near Infra-Red – Barker (1922) “Infra-red absorption bands of CO2 at 2.7 and 4.3 μ. – New absorption curves have been obtained, using a special prism-grating double spectrometer of higher resolution (Figs. 1-3). The 2.7 μ region, heretofore considered to be a doublet, proves to be a pair of doublets, with centers at approximately 2.694 μ and 2.767 μ. The 4.3 μ band appears as a single doublet with center at 4.253 μ. The frequency difference between maxima is nearly the same for each of the three doublets, and equal to 4.5 x 1011. Complete resolution of the band series was not effected, even though the slit included only 12 A for the 2.7 μ region, but there is evidently a complicated structure, with a “head” in each case on the side of shorter wave-lengths. The existence of this head for the 4.3 μ band is also indicated by a comparison with the emission spectrum from a bunsen flame, and the difference in wave-length of the maxima of emission and absorption is explained as a temperature effect similar to that observed with other doublets.” [For free full text, click PDF or GIF links in the linked abstract page]

Ueber die Bedeutung des Wasserdampfes und der Kohlensäure bei der Absorption der Erdatmosphäre – Ångström (1900)

Observations on the Absorption and Emission of Aqueous Vapor and Carbon Dioxide in the Infra-Red Spectrum – Rubens & Aschkinass (1898) “Our experiments carried out as described above on the absorption spectrum carbon dioxide very soon showed that we were dealing with a single absorption band whose maximum lies near λ = 14.7 μ. … The whole region of absorption is limited to the interval from 12.5 μ to 16 μ, with the maximum at 14.7 μ.” [For free full text, click PDF or GIF links in the linked abstract page]

On the absorption of dark heat-rays by gases and vapours – Lecher & Pernter (1881) Svante Arrhenius wrote in his famous 1897 paper: “Tyndall held the opinion that the water-vapour has the greatest influence, whilst other authors, for instance Lecher and Pernter, are inclined to think that the carbonic acid plays the more important part.”.

The Bakerian Lecture – On the Absorption and Radiation of Heat by Gases and Vapours, and on the Physical Connexion of Radiation, Absorption, and Conduction – Tyndall (1861) 150 years ago John Tyndall already showed that carbon dioxide absorbs infrared radiation. [Full text] [Wikipedia: John Tyndall]

Closely related

The HITRAN Database – The laboratory work results on the absorption properties of carbon dioxide (and many other molecules) is contained in this database.

(In accordance with Title 17 U.S.C. Section 107, this material is distributed without profit to those who have expressed a prior interest in receiving the included information for research and educational purposes.)

[ame=http://www.youtube.com/watch?v=2IlHgbOWj4o]Thomas Dolby - She Blinded Me With Science - YouTube[/ame]

 

[CrusaderFrank]

But you can't ever show us how this works in a lab, amiright?

No, of course not. You're never right. You're a completely clueless retard.

You've been shown the lab experiments supporting the Greenhouse Effect many times but you have your head jammed too far up your pansy ass to see it and you're too stupid to understand it anyway.

Anti-science reality deniers like you, frankie-boy, are always so confused and clueless.

I can't be bothered to copy all of the links and insert them so you'll just have to go to the original site to check the links.

Papers on laboratory measurements of CO2 absorption properties

September 25, 2009
(free to reproduce)

This is a list of papers on laboratory measurements of the absorption properties of carbon dioxide. In the context of these paperlists this is a difficult subject because only few of the papers are freely available online, so we have to settle on abstracts only (of course, interested reader can purchase the full texts for the papers from the linked abstract pages). However, I don’t think that matters that much because the main point of this list really is to show that the basic research on the subject exists. The list is not complete, and will most likely be updated in the future in order to make it more thorough and more representative.

UPDATE (February 6, 2010): Miller & Watts (1984) added.
UPDATE (July 25, 2010): I modified the introduction paragraph a little to reflect the current content of the list. The old text was a little outdated.
UPDATE (June 22, 2010): Lecher & Pernter (1881) added.
UPDATE (March 31, 2010): Tubbs & Williams (1972), Rubens & Aschkinass (1898) and Ångström (1900) added.
UPDATE (March 6, 2010): Barker (1922) added.
UPDATE (November 19, 2009): Predoi-Cross et al. (2007) added.
UPDATE (September 25, 2009): Miller & Brown (2004) added, thanks to John Cook for bringing it to my attention (see the discussion section below).

Spectroscopic database of CO2 line parameters: 4300–7000 cm−1 – Toth et al. (2008) “A new spectroscopic database for carbon dioxide in the near infrared is presented to support remote sensing of the terrestrial planets (Mars, Venus and the Earth). The compilation contains over 28,500 transitions of 210 bands from 4300 to 7000 cm−1…”

Line shape parameters measurement and computations for self-broadened carbon dioxide transitions in the 30012 ← 00001 and 30013 ← 00001 bands, line mixing, and speed dependence – Predoi-Cross et al. (2007) “Transitions of pure carbon dioxide have been measured using a Fourier transform spectrometer in the 30012 ← 00001 and 30013 ← 00001 vibrational bands. The room temperature spectra, recorded at a resolution of 0.008 cm−1, were analyzed using the Voigt model and a Speed Dependent Voigt line shape model that includes a pressure dependent narrowing parameter. Intensities, self-induced pressure broadening, shifts, and weak line mixing coefficients are determined. The results obtained are consistent with other studies in addition to the theoretically calculated values.” [Full text]

Spectroscopic challenges for high accuracy retrievals of atmospheric CO2 and the Orbiting Carbon Observatory (OCO) experiment – Miller et al. (2005) “The space-based Orbiting Carbon Observatory (OCO) mission will achieve global measurements needed to distinguish spatial and temporal gradients in the CO2 column. Scheduled by NASA to launch in 2008, the instrument will obtain averaged dry air mole fraction (XCO2) with a precision of 1 part per million (0.3%) in order to quantify the variation of CO2 sources and sinks and to improve future climate forecasts. Retrievals of XCO2 from ground-based measurements require even higher precisions to validate the satellite data and link them accurately and without bias to the World Meteorological Organization (WMO) standard for atmospheric CO2 observations. These retrievals will require CO2 spectroscopic parameters with unprecedented accuracy. Here we present the experimental and data analysis methods implemented in laboratory studies in order to achieve this challenging goal.”

Near infrared spectroscopy of carbon dioxide I. 16O12C16O line positions – Miller & Brown (2004) “High-resolution near-infrared (4000–9000 cm-1) spectra of carbon dioxide have been recorded using the McMath–Pierce Fourier transform spectrometer at the Kitt Peak National Solar Observatory. Some 2500 observed positions have been used to determine spectroscopic constants for 53 different vibrational states of the 16O12C16O isotopologue, including eight vibrational states for which laboratory spectra have not previously been reported. … This work reduces CO2 near-infrared line position uncertainties by a factor of 10 or more compared to the 2000 HITRAN line list, which has not been modified since the comprehensive work of Rothman et al. [J. Quant. Spectrosc. Rad. Transfer 48 (1992) 537].” [Full text]

Spectra calculations in central and wing regions of CO2 IR bands between 10 and 20 μm. I: model and laboratory measurements – Niro et al. (2004) “Temperature (200–300 K) and pressure (70–200 atm) dependent laboratory measurements of infrared transmission by CO2–N2 mixtures have been made. From these experiments the absorption coefficient is reconstructed, over a range of several orders of magnitude, between 600 and 1000 cm−1.”

Collisional effects on spectral line-shapes – Boulet (2004) “The growing concern of mankind for the understanding and preserving of its environment has stimulated great interest for the study of planetary atmospheres and, first of all, for that of the Earth. Onboard spectrometers now provide more and more precise information on the transmission and emission of radiation by these atmospheres. Its treatment by ‘retrieval’ technics, in order to extract vertical profiles (pressure, temperature, volume mixing ratios) requires precise modeling of infrared absorption spectra. Within this framework, accounting for the influence of pressure on the absorption shape is crucial. These effects of inter-molecular collisions between the optically active species and the ‘perturbers’ are complex and of various types depending mostly on the density of perturbers. The present paper attempts to review and illustrate, through a few examples, the state of the art in this field.”

On far-wing Raman profiles by CO2 – Benech et al. (2002) “Despite the excellent agreement observed in N2 here, a substantial inconsistency between theory and experiment was found in the wing of the spectrum. Although the influence of other missing processes or neighboring bands cannot be totally excluded, our findings rather suggest that highly anisotropic perturbers, such as CO2, are improperly described when they are handled as point-like molecules, a cornerstone hypothesis in the approach employed.”

Collision-induced scattering in CO2 gas – Teboul et al. (1995) “Carbon-dioxide gas rototranslational scattering has been measured at 294.5 K in the frequency range 10–1000 cm−1 at 23 amagat. The depolarization ratio of scattered intensities in the frequency range 10–1000 cm−1 is recorded. The theoretical and experimental spectra in the frequency range 10–470 cm−1 are compared.”

The HITRAN database: 1986 edition – Rothman et al. (1987) “A description and summary of the latest edition of the AFGL HITRAN molecular absorption parameters database are presented. This new database combines the information for the seven principal atmospheric absorbers and twenty-one additional molecular species previously contained on the AFGL atmospheric absorption line parameter compilation and on the trace gas compilation.”

Rotational structure in the infrared spectra of carbon dioxide and nitrous oxide dimers – Miller & Watts (1984) “High-resolution infrared predissociation spectra have been measured for dilute mixtures of CO2 and N2O in helium. Rotational fine structure is clearly resolved for both (CO2)2 and (N2O)2, the linewidths being instrument-limited. This establishes that predissociation lifetimes are longer than approximately 50 ns.”

Broadening of Infrared Absorption Lines at Reduced Temperatures: Carbon Dioxide – Tubbs & Williams (1972) “An evacuated high-resolution Czerny-Turner spectrograph, which is described in this paper, has been used to determine the strengths S and self-broadening parameters γ0 for lines in the R branch of the ν3 fundamental of 12C16O2 at 298 and at 207 K. The values of γ0 at 207 K are greater than those to be expected on the basis of a fixed collision cross section σ.”

Investigation of the Absorption of Infrared Radiation by Atmospheric Gases – Burch et al. (1970) “From spectral transmittance curves of very large samples of CO2 we have determined coefficients for intrinsic absorption and pressure-induced absorption from approximately 1130/cm to 1835/cm.”

Absorption of Infrared Radiant Energy by CO2 and H2O. IV. Shapes of Collision-Broadened CO2 Lines – Burch et al. (1969) “The shapes of the extreme wings of self-broadened CO2 lines have been investigated in three spectral regions near 7000, 3800, and 2400 cm−1. … New information has been obtained about the shapes of self-broadened CO2 lines as well as CO2 lines broadened by N2, O2, Ar, He, and H2.”

High-Temperature Spectral Emissivities and Total Intensities of the 15-µ Band System of CO2 – Ludwig et al. (1966) “Spectral-emissivity measurements of the 15-µ band of CO2 were made in the temperature range from 1000° to 2300°K.”

Line shape in the wing beyond the band head of the 4·3 μ band of CO2 – Winters et al. (1964) “Quantitative absorpance measurements have been made in pure CO2 and mixtures of CO2 with N2 and O2 in a 10 m White Perkin-Elmer cell. With absorbing paths up to 50 m-atm, results have been obtained from the band head at 2397 cm−1 to 2575 cm−1.”

Emissivity of Carbon Dioxide at 4.3 µ – Davies (1964) “The emissivity of carbon dioxide has been measured for temperatures from 1500° to 3000°K over the wavelength range from 4.40 to 5.30 µ.”

Absorption Line Broadening in the Infrared – Burch et al. (1962) “The effects of various gases on the absorption bands of nitrous oxide, carbon monoxide, methane, carbon dioxide, and water vapor have been investigated.”

Total Absorptance of Carbon Dioxide in the Infrared – Burch et al. (1962) “Total absorptance… has been determined as a function of absorber concentration w and equivalent pressure Pe for the major infrared absorption bands of carbon dioxide with centers at 3716, 3609, 2350, 1064, and 961 cm−1.”

Rotation-Vibration Spectra of Diatomic and Simple Polyatomic Molecules with Long Absorbing Paths – Herzberg & Herzberg (1953) “The spectrum of CO2 in the photographic infrared has been studied with absorbing paths up to 5500 m. Thirteen absorption bands were found of which eleven have been analyzed in detail.”

The Infrared Absorption Spectrum of Carbon Dioxide – Martin & Barker (1932) “The complete infrared spectrum of CO2 may consistently be explained in terms of a linear symmetrical model, making use of the selection rules developed by Dennison and the resonance interaction introduced by Fermi. The inactive fundamental ν1 appears only in combination bands, but ν2 at 15μ and ν3 at 4.3μ absorb intensely.”

Carbon Dioxide Absorption in the Near Infra-Red – Barker (1922) “Infra-red absorption bands of CO2 at 2.7 and 4.3 μ. – New absorption curves have been obtained, using a special prism-grating double spectrometer of higher resolution (Figs. 1-3). The 2.7 μ region, heretofore considered to be a doublet, proves to be a pair of doublets, with centers at approximately 2.694 μ and 2.767 μ. The 4.3 μ band appears as a single doublet with center at 4.253 μ. The frequency difference between maxima is nearly the same for each of the three doublets, and equal to 4.5 x 1011. Complete resolution of the band series was not effected, even though the slit included only 12 A for the 2.7 μ region, but there is evidently a complicated structure, with a “head” in each case on the side of shorter wave-lengths. The existence of this head for the 4.3 μ band is also indicated by a comparison with the emission spectrum from a bunsen flame, and the difference in wave-length of the maxima of emission and absorption is explained as a temperature effect similar to that observed with other doublets.” [For free full text, click PDF or GIF links in the linked abstract page]

Ueber die Bedeutung des Wasserdampfes und der Kohlensäure bei der Absorption der Erdatmosphäre – Ångström (1900)

Observations on the Absorption and Emission of Aqueous Vapor and Carbon Dioxide in the Infra-Red Spectrum – Rubens & Aschkinass (1898) “Our experiments carried out as described above on the absorption spectrum carbon dioxide very soon showed that we were dealing with a single absorption band whose maximum lies near λ = 14.7 μ. … The whole region of absorption is limited to the interval from 12.5 μ to 16 μ, with the maximum at 14.7 μ.” [For free full text, click PDF or GIF links in the linked abstract page]

On the absorption of dark heat-rays by gases and vapours – Lecher & Pernter (1881) Svante Arrhenius wrote in his famous 1897 paper: “Tyndall held the opinion that the water-vapour has the greatest influence, whilst other authors, for instance Lecher and Pernter, are inclined to think that the carbonic acid plays the more important part.”.

The Bakerian Lecture – On the Absorption and Radiation of Heat by Gases and Vapours, and on the Physical Connexion of Radiation, Absorption, and Conduction – Tyndall (1861) 150 years ago John Tyndall already showed that carbon dioxide absorbs infrared radiation. [Full text] [Wikipedia: John Tyndall]

Closely related

The HITRAN Database – The laboratory work results on the absorption properties of carbon dioxide (and many other molecules) is contained in this database.

(In accordance with Title 17 U.S.C. Section 107, this material is distributed without profit to those who have expressed a prior interest in receiving the included information for research and educational purposes.)

[ame=http://www.youtube.com/watch?v=2IlHgbOWj4o]Thomas Dolby - She Blinded Me With Science - YouTube[/ame]

AGW Theme song: Blinded me with bullshit

 

[whitehall]

UK blather again. UK scientists haven't been right about anything since they told the king that cigarette smoking cures stuttering. Ever consider the tons and tons of almost pure sulfuric acid that volcanoes spew into the ocean almost on a daily basis? It makes the puny smokestack technology of the last 150 years look like child's play.

 

[CrusaderFrank]

Dateline: December 2012 AGW makes Bigger Squirrels

 

[RollingThunder]

But you can't ever show us how this works in a lab, amiright?

No, of course not. You're never right. You're a completely clueless retard.

You've been shown the lab experiments supporting the Greenhouse Effect many times but you have your head jammed too far up your pansy ass to see it and you're too stupid to understand it anyway.

Anti-science reality deniers like you, frankie-boy, are always so confused and clueless.

I can't be bothered to copy all of the links and insert them so you'll just have to go to the original site to check the links.

Papers on laboratory measurements of CO2 absorption properties

September 25, 2009
(free to reproduce)

This is a list of papers on laboratory measurements of the absorption properties of carbon dioxide.

yes, the same tired old articles that don't show how AGW caused swings in temperature and turns the oceans to gastric juice

Oh, you poor brainless turd, you claim there are no lab experiments demonstrating the greenhouse gas properties of carbon dioxide and then when you are shown that there are many such experiments, you sink into even more mindless denial of reality and incoherent gibberish. What you mean is 'the same old articles' that you are too stupid to understand or even read.

 

[westwall]

No, of course not. You're never right. You're a completely clueless retard.

You've been shown the lab experiments supporting the Greenhouse Effect many times but you have your head jammed too far up your pansy ass to see it and you're too stupid to understand it anyway.



yes, the same tired old articles that don't show how AGW caused swings in temperature and turns the oceans to gastric juice

Oh, you poor brainless turd, you claim there are no lab experiments demonstrating the greenhouse gas properties of carbon dioxide and then when you are shown that there are many such experiments, you sink into even more mindless denial of reality and incoherent gibberish. What you mean is 'the same old articles' that you are too stupid to understand or even read.

Your problem, dear delusional dingbat is you don't understand the basics. The "experiments" you constantly refer to are not GHG experiments...they are Ideal Gas Law experiments. Look it up, you might learn something.

 

[Old Rocks]

The experiment has been done several times right here on Earth, involving the whole of the Earth's atmosphere and biosphere. Just because the source of the GHGs was natural in no way changes the physics of the situation. Several times there have been rapid increases and decreases in GHGs, and each time there has been an extinction event, large or small.

Extinction and Climate « ClimateSight

There have been five major extinction events in the Earth’s history, which biologists refer to as “The Big Five”. The Ordovician-Silurian, Late Devonian, Permian-Triassic, Late Triassic, Cretaceous-Tertiary…they’re a bit of a mouthful, but all five happened before humans were around, and all five are associated with climate change. Let’s look at a few examples.

The most recent extinction event, the Cretaceous-Tertiary (K-T) extinction, is also the most well-known and extensively studied: it’s the event that killed the dinosaurs. Scientists are quite sure that the trigger for this extinction was an asteroid that crashed into the planet, leaving a crater near the present-day Yucatan Peninsula of Mexico. Devastation at the site would have been massive, but it was the indirect, climatic effects of the impact that killed species across the globe. Most prominently, dust and aerosols kicked up by the asteroid became trapped in the atmosphere, blocking and reflecting sunlight. As well as causing a dramatic, short-term cooling, the lack of sunlight reaching the Earth inhibited photosynthesis, so many plant species became extinct. This effect was carried up the food chain, as first herbivorous, then carnivorous, species became extinct. Dinosaurs, the dominant life form during the Cretaceous Period, completely died out, while insects, early mammals, and bird-like reptiles survived, as their small size and scavenging habits made it easier to find food.

However, life on Earth has been through worse than this apocalyptic scenario. The
largest extinction in the Earth’s history, the Permian-Triassic extinction, occurred about 250 million years ago, right before the time of the dinosaurs. Up to 95% of all species on Earth were killed in this event, and life in the oceans was particularly hard-hit. It took 100 million years for the remaining species to recover from this extinction, nicknamed “The Great Dying”, and we are very lucky that life recovered at all.

 

[westwall]

The experiment has been done several times right here on Earth, involving the whole of the Earth's atmosphere and biosphere. Just because the source of the GHGs was natural in no way changes the physics of the situation. Several times there have been rapid increases and decreases in GHGs, and each time there has been an extinction event, large or small.

Extinction and Climate « ClimateSight

There have been five major extinction events in the Earth’s history, which biologists refer to as “The Big Five”. The Ordovician-Silurian, Late Devonian, Permian-Triassic, Late Triassic, Cretaceous-Tertiary…they’re a bit of a mouthful, but all five happened before humans were around, and all five are associated with climate change. Let’s look at a few examples.

The most recent extinction event, the Cretaceous-Tertiary (K-T) extinction, is also the most well-known and extensively studied: it’s the event that killed the dinosaurs. Scientists are quite sure that the trigger for this extinction was an asteroid that crashed into the planet, leaving a crater near the present-day Yucatan Peninsula of Mexico. Devastation at the site would have been massive, but it was the indirect, climatic effects of the impact that killed species across the globe. Most prominently, dust and aerosols kicked up by the asteroid became trapped in the atmosphere, blocking and reflecting sunlight. As well as causing a dramatic, short-term cooling, the lack of sunlight reaching the Earth inhibited photosynthesis, so many plant species became extinct. This effect was carried up the food chain, as first herbivorous, then carnivorous, species became extinct. Dinosaurs, the dominant life form during the Cretaceous Period, completely died out, while insects, early mammals, and bird-like reptiles survived, as their small size and scavenging habits made it easier to find food.

However, life on Earth has been through worse than this apocalyptic scenario. The
largest extinction in the Earth’s history, the Permian-Triassic extinction, occurred about 250 million years ago, right before the time of the dinosaurs. Up to 95% of all species on Earth were killed in this event, and life in the oceans was particularly hard-hit. It took 100 million years for the remaining species to recover from this extinction, nicknamed “The Great Dying”, and we are very lucky that life recovered at all.

And not a single one of those has been tied to warming. Cooling possibly, but never warming....except in the fevered imaginations of people who think the movie 2012 was a documentary.

 

[RollingThunder]

The experiment has been done several times right here on Earth, involving the whole of the Earth's atmosphere and biosphere. Just because the source of the GHGs was natural in no way changes the physics of the situation. Several times there have been rapid increases and decreases in GHGs, and each time there has been an extinction event, large or small.

Extinction and Climate « ClimateSight

There have been five major extinction events in the Earth’s history, which biologists refer to as “The Big Five”. The Ordovician-Silurian, Late Devonian, Permian-Triassic, Late Triassic, Cretaceous-Tertiary…they’re a bit of a mouthful, but all five happened before humans were around, and all five are associated with climate change. Let’s look at a few examples.

The most recent extinction event, the Cretaceous-Tertiary (K-T) extinction, is also the most well-known and extensively studied: it’s the event that killed the dinosaurs. Scientists are quite sure that the trigger for this extinction was an asteroid that crashed into the planet, leaving a crater near the present-day Yucatan Peninsula of Mexico. Devastation at the site would have been massive, but it was the indirect, climatic effects of the impact that killed species across the globe. Most prominently, dust and aerosols kicked up by the asteroid became trapped in the atmosphere, blocking and reflecting sunlight. As well as causing a dramatic, short-term cooling, the lack of sunlight reaching the Earth inhibited photosynthesis, so many plant species became extinct. This effect was carried up the food chain, as first herbivorous, then carnivorous, species became extinct. Dinosaurs, the dominant life form during the Cretaceous Period, completely died out, while insects, early mammals, and bird-like reptiles survived, as their small size and scavenging habits made it easier to find food.

However, life on Earth has been through worse than this apocalyptic scenario. The
largest extinction in the Earth’s history, the Permian-Triassic extinction, occurred about 250 million years ago, right before the time of the dinosaurs. Up to 95% of all species on Earth were killed in this event, and life in the oceans was particularly hard-hit. It took 100 million years for the remaining species to recover from this extinction, nicknamed “The Great Dying”, and we are very lucky that life recovered at all.

And not a single one of those has been tied to warming. Cooling possibly, but never warming....except in the fevered imaginations of people who think the movie 2012 was a documentary.

Oh, you poor ignorant wacko....

It has been obvious for some time now that whenever you're confronted with information you don't like, you just make up some BS that you imagine will 'refute' the info. LOLOLOLOL. Such a clueless crazy little wacko.

The extinction events mostly seem to be tied to warming according to the scientific evidence and only once, in the Ordovician period, does one seem to be linked to cooling.

Mass Extinctions Tied to Past Climate Changes
Fossil and temperature records over the past 520 million years show a correlation between extinctions and climate change
By David Biello
Scientific American
October 24, 2007
(excerpts)

Roughly 251 million years ago, an estimated 70 percent of land plants and animals died, along with 84 percent of ocean organisms—an event known as the end Permian extinction. The cause is unknown but it is known that this period was also an extremely warm one. A new analysis of the temperature and fossil records over the past 520 million years reveals that the end of the Permian is not alone in this association: global warming is consistently associated with planetwide die-offs. "There have been three major greenhouse phases in the time period we analyzed and the peaks in temperature of each coincide with mass extinctions," says ecologist Peter Mayhew of the University of York in England, who led the research examining the fossil and temperature records. "The fossil record and temperature data sets already existed but nobody had looked at the relationships between them."

Pairing these data—the relative number of different shallow sea organisms extant during a given time period and the record of temperature encased in the varying levels of oxygen isotopes in their shells over 10 million year intervals—reveals that eras with relatively high concentrations of greenhouse gases bode ill for the number of species on Earth. "The rule appears to be that greenhouse worlds adversely affect biodiversity," Mayhew says. That also bodes ill for the fate of species currently on Earth as the global temperatures continue to rise to levels similar to those seen during the Permian. "The risk of future extinction through rapid global warming is primarily expected to occur through mismatches between the climates to which organisms are adapted in their current range and the future distribution of those climates," Mayhew and his colleagues write in Proceedings of the Royal Society B: Biological Sciences, though it may also be that warmer temperatures lead to less hospitable seas, he adds.

 

[westwall]

The experiment has been done several times right here on Earth, involving the whole of the Earth's atmosphere and biosphere. Just because the source of the GHGs was natural in no way changes the physics of the situation. Several times there have been rapid increases and decreases in GHGs, and each time there has been an extinction event, large or small.

Extinction and Climate « ClimateSight

There have been five major extinction events in the Earth’s history, which biologists refer to as “The Big Five”. The Ordovician-Silurian, Late Devonian, Permian-Triassic, Late Triassic, Cretaceous-Tertiary…they’re a bit of a mouthful, but all five happened before humans were around, and all five are associated with climate change. Let’s look at a few examples.

The most recent extinction event, the Cretaceous-Tertiary (K-T) extinction, is also the most well-known and extensively studied: it’s the event that killed the dinosaurs. Scientists are quite sure that the trigger for this extinction was an asteroid that crashed into the planet, leaving a crater near the present-day Yucatan Peninsula of Mexico. Devastation at the site would have been massive, but it was the indirect, climatic effects of the impact that killed species across the globe. Most prominently, dust and aerosols kicked up by the asteroid became trapped in the atmosphere, blocking and reflecting sunlight. As well as causing a dramatic, short-term cooling, the lack of sunlight reaching the Earth inhibited photosynthesis, so many plant species became extinct. This effect was carried up the food chain, as first herbivorous, then carnivorous, species became extinct. Dinosaurs, the dominant life form during the Cretaceous Period, completely died out, while insects, early mammals, and bird-like reptiles survived, as their small size and scavenging habits made it easier to find food.

However, life on Earth has been through worse than this apocalyptic scenario. The
largest extinction in the Earth’s history, the Permian-Triassic extinction, occurred about 250 million years ago, right before the time of the dinosaurs. Up to 95% of all species on Earth were killed in this event, and life in the oceans was particularly hard-hit. It took 100 million years for the remaining species to recover from this extinction, nicknamed “The Great Dying”, and we are very lucky that life recovered at all.

And not a single one of those has been tied to warming. Cooling possibly, but never warming....except in the fevered imaginations of people who think the movie 2012 was a documentary.

Oh, you poor ignorant wacko....

It has been obvious for some time now that whenever you're confronted with information you don't like, you just make up some BS that you imagine will 'refute' the info. LOLOLOLOL. Such a clueless crazy little wacko.

The extinction events mostly seem to be tied to warming according to the scientific evidence and only once, in the Ordovician period, does one seem to be linked to cooling.

Mass Extinctions Tied to Past Climate Changes
Fossil and temperature records over the past 520 million years show a correlation between extinctions and climate change
By David Biello
Scientific American
October 24, 2007
(excerpts)

Roughly 251 million years ago, an estimated 70 percent of land plants and animals died, along with 84 percent of ocean organisms—an event known as the end Permian extinction. The cause is unknown but it is known that this period was also an extremely warm one. A new analysis of the temperature and fossil records over the past 520 million years reveals that the end of the Permian is not alone in this association: global warming is consistently associated with planetwide die-offs. "There have been three major greenhouse phases in the time period we analyzed and the peaks in temperature of each coincide with mass extinctions," says ecologist Peter Mayhew of the University of York in England, who led the research examining the fossil and temperature records. "The fossil record and temperature data sets already existed but nobody had looked at the relationships between them."

Pairing these data—the relative number of different shallow sea organisms extant during a given time period and the record of temperature encased in the varying levels of oxygen isotopes in their shells over 10 million year intervals—reveals that eras with relatively high concentrations of greenhouse gases bode ill for the number of species on Earth. "The rule appears to be that greenhouse worlds adversely affect biodiversity," Mayhew says. That also bodes ill for the fate of species currently on Earth as the global temperatures continue to rise to levels similar to those seen during the Permian. "The risk of future extinction through rapid global warming is primarily expected to occur through mismatches between the climates to which organisms are adapted in their current range and the future distribution of those climates," Mayhew and his colleagues write in Proceedings of the Royal Society B: Biological Sciences, though it may also be that warmer temperatures lead to less hospitable seas, he adds.

What was that poor delusional dingbat? Below are the most likely possible reasons. You will note that under climate change they only look at cold as a killer. Warmth has never (until you religious nut cases dreamed it up) been associated with mass extinctions. Quite the opposite in fact.

Some of the hypotheses for the causes of mass extinction events are:.
1.Impact events. The impact of a sufficiently large asteroid or comet could create large tsunamis, global forest fires, and reduction of incoming sunlight due to large amounts of dust and smoke in the atmosphere. Taken together, it is not surprising that these and other related effects from an impact event might be sufficiently severe as to disrupt the global ecosystem and cause extinctions. Only for the End Cretaceous extinction (about 65 mya) is there strong evidence of such an impact. Circumstantial evidence of such events is also given for the End Ordovician extinction (about 444 mya), End Permian extinction (about 251 mya), End Jurassic extinction (about 145 mya), and End Eocene extinction (about 40 mya).
2.Climate change. Rapid transitions in climate may be capable of stressing the environment to the point of extinction. However, it is worth observing that the recent cycles of ice ages are believed to have had only very mild impacts on biodiversity. Extinctions suggested to have this cause include: End Ordovician (about 444 mya), End Permian (about 251 mya), and Late Devonian (about 360 mya).
3.Volcanism. The formation of large igneous provinces through the outflow of up to millions of cubic kilometers of lava in a short duration is likely to poison the atmosphere and oceans in a way that may cause extinctions. This cause has been proposed for the End Cretaceous extinction (about 65 mya), End Permian extinction (about 251 mya), End Triassic extinction (about 200 mya), and End Jurassic extinction (about 145 mya).
4.Gamma ray burst. A nearby gamma ray burst (less than 6,000 light years distance) could destroy the ozone layer and sufficiently irradiate the surface of the Earth to kill organisms living there. From statistical arguments, approximately 1 gamma ray burst would be expected to occur in close proximity to Earth in the last 540 million years. This has been suggested as a possible explanation for the End Ordovician extinction (about 444 mya). However, a recent study by leading gamma ray burst researchers says that gamma ray bursts are not possible in metal rich galaxies like our own (Stanek et al. 2006).
5.Plate tectonics. The opening and closing of seaways and land bridges may play a role in extinction events as previously isolated populations are brought into contact and new dynamics are established in the ecosystem. This is most frequently discussed in relation to the End Permian extinction (about 251 mya).

Other hypotheses, such as the spread of a new disease or simple competition following an especially successful biological innovation are also considered. However, it is often thought that the major mass extinctions in Earth's history are too sudden and too extensive to have resulted solely from biological events."


Mass extinction - New World Encyclopedia

 

[techieny]

Did someone mention acid. I'll volunteer for the trial. Do I have to inject it, swallow it, or just take a swim???

 

[CrusaderFrank]

The experiment has been done several times right here on Earth, involving the whole of the Earth's atmosphere and biosphere. Just because the position of Venus and Jupiter was natural in no way changes the physics of the situation. Several times there have been rapid increases and decreases in your fortunes, and each time there has been an some astrological explanation.

There OR fixed it so your AGW is indistinguishable from astrology

 

[RollingThunder]

And not a single one of those has been tied to warming. Cooling possibly, but never warming....except in the fevered imaginations of people who think the movie 2012 was a documentary.

Oh, you poor ignorant wacko....

It has been obvious for some time now that whenever you're confronted with information you don't like, you just make up some BS that you imagine will 'refute' the info. LOLOLOLOL. Such a clueless crazy little wacko.

The extinction events mostly seem to be tied to warming according to the scientific evidence and only once, in the Ordovician period, does one seem to be linked to cooling.

Mass Extinctions Tied to Past Climate Changes
Fossil and temperature records over the past 520 million years show a correlation between extinctions and climate change
By David Biello
Scientific American
October 24, 2007
(excerpts)

Roughly 251 million years ago, an estimated 70 percent of land plants and animals died, along with 84 percent of ocean organisms—an event known as the end Permian extinction. The cause is unknown but it is known that this period was also an extremely warm one. A new analysis of the temperature and fossil records over the past 520 million years reveals that the end of the Permian is not alone in this association: global warming is consistently associated with planetwide die-offs. "There have been three major greenhouse phases in the time period we analyzed and the peaks in temperature of each coincide with mass extinctions," says ecologist Peter Mayhew of the University of York in England, who led the research examining the fossil and temperature records. "The fossil record and temperature data sets already existed but nobody had looked at the relationships between them."

Pairing these data—the relative number of different shallow sea organisms extant during a given time period and the record of temperature encased in the varying levels of oxygen isotopes in their shells over 10 million year intervals—reveals that eras with relatively high concentrations of greenhouse gases bode ill for the number of species on Earth. "The rule appears to be that greenhouse worlds adversely affect biodiversity," Mayhew says. That also bodes ill for the fate of species currently on Earth as the global temperatures continue to rise to levels similar to those seen during the Permian. "The risk of future extinction through rapid global warming is primarily expected to occur through mismatches between the climates to which organisms are adapted in their current range and the future distribution of those climates," Mayhew and his colleagues write in Proceedings of the Royal Society B: Biological Sciences, though it may also be that warmer temperatures lead to less hospitable seas, he adds.

What was that poor delusional dingbat? Below are the most likely possible reasons. You will note that under climate change they only look at cold as a killer. Warmth has never (until you religious nut cases dreamed it up) been associated with mass extinctions. Quite the opposite in fact.

Liar!!! The encyclopedia entry mentions "rapid transitions in climate" and doesn't "look at cold as a killer" at all except to say that the ice ages don't appear to have much effect on biodiversity.

2.Climate change. Rapid transitions in climate may be capable of stressing the environment to the point of extinction. However, it is worth observing that the recent cycles of ice ages are believed to have had only very mild impacts on biodiversity. Extinctions suggested to have this cause include: End Ordovician (about 444 mya), End Permian (about 251 mya), and Late Devonian (about 360 mya).

The Ordovician is the only one linked to increasing cold rather than increasing warming.

In any case, regardless of what happened in the distant past, this is what we facing now.

Global Warming Capable Of Sparking Mass Species Extinctions
ScienceDaily
Apr. 11, 2006
(excerpts)

The Earth could see massive waves of species extinctions around the world if global warming continues unabated, according to a new study published in the scientific journal Conservation Biology. Given its potential to damage areas far away from human habitation, the study finds that global warming represents one of the most pervasive threats to our planet's biodiversity -- in some areas rivaling and even surpassing deforestation as the main threat to biodiversity.

The study expands on a much-debated 2004 paper published in the journal Nature that suggested a quarter of the world's species would be committed to extinction by 2050 as a result of global warming. This latest study picks up where the Nature paper left off, incorporating critiques and suggestions from other scientists while increasing the global scope of the research to include diverse hotspots around the world. The results reinforce the massive species extinction risks identified in the 2004 study. "Climate change is rapidly becoming the most serious threats to the planet's biodiversity," said lead author Dr. Jay Malcolm, an assistant forestry professor at the University of Toronto. "This study provides even stronger scientific evidence that global warming will result in catastrophic species loss across the planet."

 

[skookerasbil]

Oh, you poor ignorant wacko....

It has been obvious for some time now that whenever you're confronted with information you don't like, you just make up some BS that you imagine will 'refute' the info. LOLOLOLOL. Such a clueless crazy little wacko.

The extinction events mostly seem to be tied to warming according to the scientific evidence and only once, in the Ordovician period, does one seem to be linked to cooling.

Mass Extinctions Tied to Past Climate Changes
Fossil and temperature records over the past 520 million years show a correlation between extinctions and climate change
By David Biello
Scientific American
October 24, 2007
(excerpts)

Roughly 251 million years ago, an estimated 70 percent of land plants and animals died, along with 84 percent of ocean organisms—an event known as the end Permian extinction. The cause is unknown but it is known that this period was also an extremely warm one. A new analysis of the temperature and fossil records over the past 520 million years reveals that the end of the Permian is not alone in this association: global warming is consistently associated with planetwide die-offs. "There have been three major greenhouse phases in the time period we analyzed and the peaks in temperature of each coincide with mass extinctions," says ecologist Peter Mayhew of the University of York in England, who led the research examining the fossil and temperature records. "The fossil record and temperature data sets already existed but nobody had looked at the relationships between them."

Pairing these data—the relative number of different shallow sea organisms extant during a given time period and the record of temperature encased in the varying levels of oxygen isotopes in their shells over 10 million year intervals—reveals that eras with relatively high concentrations of greenhouse gases bode ill for the number of species on Earth. "The rule appears to be that greenhouse worlds adversely affect biodiversity," Mayhew says. That also bodes ill for the fate of species currently on Earth as the global temperatures continue to rise to levels similar to those seen during the Permian. "The risk of future extinction through rapid global warming is primarily expected to occur through mismatches between the climates to which organisms are adapted in their current range and the future distribution of those climates," Mayhew and his colleagues write in Proceedings of the Royal Society B: Biological Sciences, though it may also be that warmer temperatures lead to less hospitable seas, he adds.

What was that poor delusional dingbat? Below are the most likely possible reasons. You will note that under climate change they only look at cold as a killer. Warmth has never (until you religious nut cases dreamed it up) been associated with mass extinctions. Quite the opposite in fact.

Liar!!! The encyclopedia entry mentions "rapid transitions in climate" and doesn't "look at cold as a killer" at all except to say that the ice ages don't appear to have much effect on biodiversity.

2.Climate change. Rapid transitions in climate may be capable of stressing the environment to the point of extinction. However, it is worth observing that the recent cycles of ice ages are believed to have had only very mild impacts on biodiversity. Extinctions suggested to have this cause include: End Ordovician (about 444 mya), End Permian (about 251 mya), and Late Devonian (about 360 mya).

The Ordovician is the only one linked to increasing cold rather than increasing warming.

In any case, regardless of what happened in the distant past, this is what we facing now.

Global Warming Capable Of Sparking Mass Species Extinctions
ScienceDaily
Apr. 11, 2006
(excerpts)

The Earth could see massive waves of species extinctions around the world if global warming continues unabated, according to a new study published in the scientific journal Conservation Biology. Given its potential to damage areas far away from human habitation, the study finds that global warming represents one of the most pervasive threats to our planet's biodiversity -- in some areas rivaling and even surpassing deforestation as the main threat to biodiversity.

The study expands on a much-debated 2004 paper published in the journal Nature that suggested a quarter of the world's species would be committed to extinction by 2050 as a result of global warming. This latest study picks up where the Nature paper left off, incorporating critiques and suggestions from other scientists while increasing the global scope of the research to include diverse hotspots around the world. The results reinforce the massive species extinction risks identified in the 2004 study. "Climate change is rapidly becoming the most serious threats to the planet's biodiversity," said lead author Dr. Jay Malcolm, an assistant forestry professor at the University of Toronto. "This study provides even stronger scientific evidence that global warming will result in catastrophic species loss across the planet."

[ame=http://www.youtube.com/watch?v=2IlHgbOWj4o]Thomas Dolby - She Blinded Me With Science - YouTube[/ame]

Hey asshole...........almost 16 weeks. Whats up with that?

 

[RollingThunder]

almost 16 weeks

....since your brain finally died completely? I could have sworn it was much longer than that.