So, the answer is 1/3. (depotoo knew this already)
Why?
There are four equally likely possibilities (in this case, permutations) for two siblings, oldest listed first:
BB
BG
GB
GG
We have met one sibling, and she is a girl. So now, there exist three equally likely possibilities:
BG
GB
GG
As these are equally likely, the probability of each possible permutation is now 1/3. So, the probability that the other sibling is also a girl is 1/3.
Had you been given the information of whether the girl we met was the older or younger sibling, the answer would have been 1/2.