The current concentration of CO2 in the atmosphere is around 430 ppm (parts per million).
A hydrogen cyanide concentration of 150 ppm in the air is fatal to humans.
Depending on the substance and the system, small amounts can have big effects.
The fact that the minuscule quantities of CO2 and other GHGs have major effects on the climate is not only settled science, completely uncontroversial, it has been settled science for over a century. As this article explains.
<p>An enhanced greenhouse effect from CO2 has been confirmed by multiple lines of empirical evidence. Satellite measurements of infrared spectra over the past 40 years observe less energy escaping to space at the wavelengths associated with CO2. Surface measurements find more downward infrared...
skepticalscience.com
More generally, why do you think know better than the tens of thousands of PhDs working in this and related fields?
It's not "my" list, it's Wikipedia's. But yes, as nations, they should be at or near the top.
Per-capita emissions however are another matter.